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A new thin film photochromic material: Oxygen-containing yttrium hydride

  • Trygve Mongstad*
  • , Charlotte Platzer-Björkman
  • , Jan Petter Maehlen
  • , Lennard P.A. Mooij
  • , Yevheniy Pivak
  • , Bernard Dam
  • , Erik S. Marstein
  • , Bjørn C. Hauback
  • , Smagul Zh Karazhanov
  • *Corresponding author for this work
  • Institute for Energy Technology
  • Uppsala University
  • Delft University of Technology

Research output: Contribution to journalArticlepeer-review

123 Citations (Scopus)

Abstract

In this work we report on photochromism in transparent thin film samples of oxygen-containing yttrium hydride. Exposure to visible and ultraviolet (UV) light at moderate intensity triggers a decrease in the optical transmission of visible and infrared (IR) light. The photo-darkening is colour-neutral. We show that the optical transmission of samples of 500 nm thickness can be reduced by up to 50% after one hour of illumination with light of moderate intensity. The reaction is reversible and samples that are left in the dark return to the initial transparent state. The relaxation time in the dark depends on the temperature of the sample and the duration of the light exposure. The photochromic reaction takes place under ambient conditions in the as-deposited state of the thin-film samples.

Original languageEnglish
Pages (from-to)3596-3599
Number of pages4
JournalSolar Energy Materials and Solar Cells
Volume95
Issue number12
DOIs
Publication statusPublished - Dec 2011
Externally publishedYes

Keywords

  • Hydrogen
  • Photochromism
  • Photoconductivity
  • Sputter deposition
  • Thin films
  • Yttrium compounds

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