Charge transport layer doping influence on perovskite CH3NH3Pbi3-XClX solar cell performance

Anastasija Ivanova; Kristina Lebedeva; Andrey Tokmakov; Modris Roze; Igors Kaulachs

doi:10.4028/www.scientific.net/KEM.762.249

Charge transport layer doping influence on perovskite CH₃NH₃Pbi_3-XCl_X solar cell performance

Anastasija Ivanova^*
, Kristina Lebedeva
, Andrey Tokmakov
, Modris Roze
, Igors Kaulachs

^*Corresponding author for this work

Laboratory of Organic Materials, Institute of Solid State Physics

Institute of Physical Energetics
Riga Technical University

Research output: Chapter in Book/Report/Conference proceeding › Conference paper › Research › peer-review

Abstract

Organometal hybrid trihalide perovskite solar cells (PSCs) have emerged a new class of optoelectronic devices for various applications. PSCs have demonstrated unprecedented progress in efficiency reaching certified power conversion efficiency up to 22.1% after only several years of active research. In this paper, we demonstrate inverted planar mixed halide perovskite solar cells where perovskite layers are built by two-step modified interdifussion and one-step methods. We demonstrate how PSC parameters change by doping electron transport layer (ETL). We used N,N-dimethyl-N-octadecyl(3-aminopropyl) trimethoxysilyl chloride (DMOAP) as dopant for ETL [6,6]-phenyl C₆₁ butyric acid methyl ester (PCBM). The highest EQE and V_oc values were obtained for cell prepared by one-step method with fast crystallization and doped ETL but higher fill factor (FF) and shunt resistance (R_shunt) values were obtained for cells prepared by two-step method with undoped ETL.

Original language	English
Title of host publication	Materials Science and Applied Chemistry - 58th International Conference of Materials Science and Applied Chemistry, MSAC 2017
Editors	Valdis Kokars
Publisher	Trans Tech Publications Ltd
Pages	249-254
Number of pages	6
ISBN (Print)	9783035712384
DOIs	https://doi.org/10.4028/www.scientific.net/KEM.762.249
Publication status	Published - 2018
Event	58th International Conference of Materials Science and Applied Chemistry, MSAC 2017 - Riga, Latvia Duration: 20 Oct 2017 → 20 Oct 2017

Publication series

Name	Key Engineering Materials
Volume	762
ISSN (Print)	1013-9826
ISSN (Electronic)	1662-9795

Conference

Conference	58th International Conference of Materials Science and Applied Chemistry, MSAC 2017
Country/Territory	Latvia
City	Riga
Period	20/10/17 → 20/10/17

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Inverted structure
Mixed halide cells
Perovskite solar cells
Photovoltaics
Planar heterojunction

Access to Document

10.4028/www.scientific.net/KEM.762.249

Cite this

Ivanova, A., Lebedeva, K., Tokmakov, A., Roze, M., & Kaulachs, I. (2018). Charge transport layer doping influence on perovskite CH₃NH₃Pbi_3-XCl_X solar cell performance. In V. Kokars (Ed.), Materials Science and Applied Chemistry - 58th International Conference of Materials Science and Applied Chemistry, MSAC 2017 (pp. 249-254). (Key Engineering Materials; Vol. 762). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/KEM.762.249

Ivanova, Anastasija ; Lebedeva, Kristina ; Tokmakov, Andrey et al. / Charge transport layer doping influence on perovskite CH₃NH₃Pbi_3-XCl_X solar cell performance. Materials Science and Applied Chemistry - 58th International Conference of Materials Science and Applied Chemistry, MSAC 2017. editor / Valdis Kokars. Trans Tech Publications Ltd, 2018. pp. 249-254 (Key Engineering Materials).

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title = "Charge transport layer doping influence on perovskite CH3NH3Pbi3-XClX solar cell performance",

abstract = "Organometal hybrid trihalide perovskite solar cells (PSCs) have emerged a new class of optoelectronic devices for various applications. PSCs have demonstrated unprecedented progress in efficiency reaching certified power conversion efficiency up to 22.1\% after only several years of active research. In this paper, we demonstrate inverted planar mixed halide perovskite solar cells where perovskite layers are built by two-step modified interdifussion and one-step methods. We demonstrate how PSC parameters change by doping electron transport layer (ETL). We used N,N-dimethyl-N-octadecyl(3-aminopropyl) trimethoxysilyl chloride (DMOAP) as dopant for ETL [6,6]-phenyl C61 butyric acid methyl ester (PCBM). The highest EQE and Voc values were obtained for cell prepared by one-step method with fast crystallization and doped ETL but higher fill factor (FF) and shunt resistance (Rshunt) values were obtained for cells prepared by two-step method with undoped ETL.",

keywords = "Inverted structure, Mixed halide cells, Perovskite solar cells, Photovoltaics, Planar heterojunction",

author = "Anastasija Ivanova and Kristina Lebedeva and Andrey Tokmakov and Modris Roze and Igors Kaulachs",

note = "Publisher Copyright: {\textcopyright} 2018 Trans Tech Publications, Switzerland.; 58th International Conference of Materials Science and Applied Chemistry, MSAC 2017 ; Conference date: 20-10-2017 Through 20-10-2017",

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language = "English",

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Ivanova, A, Lebedeva, K, Tokmakov, A, Roze, M & Kaulachs, I 2018, Charge transport layer doping influence on perovskite CH₃NH₃Pbi_3-XCl_X solar cell performance. in V Kokars (ed.), Materials Science and Applied Chemistry - 58th International Conference of Materials Science and Applied Chemistry, MSAC 2017. Key Engineering Materials, vol. 762, Trans Tech Publications Ltd, pp. 249-254, 58th International Conference of Materials Science and Applied Chemistry, MSAC 2017, Riga, Latvia, 20/10/17. https://doi.org/10.4028/www.scientific.net/KEM.762.249

Charge transport layer doping influence on perovskite CH₃NH₃Pbi_3-XCl_X solar cell performance. / Ivanova, Anastasija; Lebedeva, Kristina; Tokmakov, Andrey et al.
Materials Science and Applied Chemistry - 58th International Conference of Materials Science and Applied Chemistry, MSAC 2017. ed. / Valdis Kokars. Trans Tech Publications Ltd, 2018. p. 249-254 (Key Engineering Materials; Vol. 762).

Research output: Chapter in Book/Report/Conference proceeding › Conference paper › Research › peer-review

TY - GEN

T1 - Charge transport layer doping influence on perovskite CH3NH3Pbi3-XClX solar cell performance

AU - Ivanova, Anastasija

AU - Lebedeva, Kristina

AU - Tokmakov, Andrey

AU - Roze, Modris

AU - Kaulachs, Igors

PY - 2018

Y1 - 2018

N2 - Organometal hybrid trihalide perovskite solar cells (PSCs) have emerged a new class of optoelectronic devices for various applications. PSCs have demonstrated unprecedented progress in efficiency reaching certified power conversion efficiency up to 22.1% after only several years of active research. In this paper, we demonstrate inverted planar mixed halide perovskite solar cells where perovskite layers are built by two-step modified interdifussion and one-step methods. We demonstrate how PSC parameters change by doping electron transport layer (ETL). We used N,N-dimethyl-N-octadecyl(3-aminopropyl) trimethoxysilyl chloride (DMOAP) as dopant for ETL [6,6]-phenyl C61 butyric acid methyl ester (PCBM). The highest EQE and Voc values were obtained for cell prepared by one-step method with fast crystallization and doped ETL but higher fill factor (FF) and shunt resistance (Rshunt) values were obtained for cells prepared by two-step method with undoped ETL.

AB - Organometal hybrid trihalide perovskite solar cells (PSCs) have emerged a new class of optoelectronic devices for various applications. PSCs have demonstrated unprecedented progress in efficiency reaching certified power conversion efficiency up to 22.1% after only several years of active research. In this paper, we demonstrate inverted planar mixed halide perovskite solar cells where perovskite layers are built by two-step modified interdifussion and one-step methods. We demonstrate how PSC parameters change by doping electron transport layer (ETL). We used N,N-dimethyl-N-octadecyl(3-aminopropyl) trimethoxysilyl chloride (DMOAP) as dopant for ETL [6,6]-phenyl C61 butyric acid methyl ester (PCBM). The highest EQE and Voc values were obtained for cell prepared by one-step method with fast crystallization and doped ETL but higher fill factor (FF) and shunt resistance (Rshunt) values were obtained for cells prepared by two-step method with undoped ETL.

KW - Inverted structure

KW - Mixed halide cells

KW - Perovskite solar cells

KW - Photovoltaics

KW - Planar heterojunction

UR - https://www.scopus.com/pages/publications/85043588249

U2 - 10.4028/www.scientific.net/KEM.762.249

DO - 10.4028/www.scientific.net/KEM.762.249

M3 - Conference paper

AN - SCOPUS:85043588249

SN - 9783035712384

T3 - Key Engineering Materials

SP - 249

EP - 254

BT - Materials Science and Applied Chemistry - 58th International Conference of Materials Science and Applied Chemistry, MSAC 2017

A2 - Kokars, Valdis

PB - Trans Tech Publications Ltd

T2 - 58th International Conference of Materials Science and Applied Chemistry, MSAC 2017

Y2 - 20 October 2017 through 20 October 2017

ER -

Ivanova A, Lebedeva K, Tokmakov A, Roze M, Kaulachs I. Charge transport layer doping influence on perovskite CH₃NH₃Pbi_3-XCl_X solar cell performance. In Kokars V, editor, Materials Science and Applied Chemistry - 58th International Conference of Materials Science and Applied Chemistry, MSAC 2017. Trans Tech Publications Ltd. 2018. p. 249-254. (Key Engineering Materials). doi: 10.4028/www.scientific.net/KEM.762.249