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Complex dielectric function in lead-free NKN films

  • R. Schwarz*
  • , R. Ayouchi
  • , S. R. Bhattacharyya
  • , M. Leal
  • , U. Mardolcar
  • , L. Santos
  • , I. Bdikin
  • , R. Rai
  • , I. Coondoo
  • , A. Kholkin
  • *Corresponding author for this work
  • University of Lisbon
  • University of Aveiro

Research output: Chapter in Book/Report/Conference proceedingConference paperResearchpeer-review

1 Citation (Scopus)

Abstract

We use optical transmission spectroscopy and spectral ellipsometry (SE) to determine the real and imaginary part of the complex dielectric function in both ceramic samples and thin films of lead-free Na xK 1-xNbO 3 (NKN). Thin films of NKN were prepared by pulsed laser deposition (PLD) from ceramic NKN targets. The optical band gap from transmission measurements in thin films yield an optical band gap of 3.94 or 3.55 eV, depending on whether direct or indirect transitions, respectively, are assumed. The fit procedure of SE results, based on the Tauc-Lorentz model, resulted in a band gap for films of 3.66 eV, whereas the band gap of the thick ceramic samples was 3.79 eV. Examples of amorphous and highly polycrystalline thin films, deposited at 450 and 600°C, respectively, are discussed.

Original languageEnglish
Title of host publicationProc. of 2012 21st IEEE International Symposium on Applications of Ferroelectrics Held Jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE, ISAF/ECAPD/PFM 2012
DOIs
Publication statusPublished - 2012
Externally publishedYes
Event2012 21st IEEE Int. Symp. on Applications of Ferroelectrics Held with 11th IEEE European Conf. on Applications of Polar Dielectrics and 4th IEEE Int. Symp on Piezoresponse Force Microscopy and Nanoscale Phenomena in Polar Materials, ISAF/ECAPD/PFM - Aveiro, Portugal
Duration: 9 Jul 201213 Jul 2012

Publication series

NameProceedings of 2012 21st IEEE Int. Symp. on Applications of Ferroelectrics held jointly with 11th IEEE European Conference on the Applications of Polar Dielectrics and IEEE PFM, ISAF/ECAPD/PFM 2012

Conference

Conference2012 21st IEEE Int. Symp. on Applications of Ferroelectrics Held with 11th IEEE European Conf. on Applications of Polar Dielectrics and 4th IEEE Int. Symp on Piezoresponse Force Microscopy and Nanoscale Phenomena in Polar Materials, ISAF/ECAPD/PFM
Country/TerritoryPortugal
CityAveiro
Period9/07/1213/07/12

Keywords

  • Dielectric function
  • NKN
  • PLD
  • spectral ellipsometry
  • thin film

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