Copper-Catalyzed para-Selective C-H Amination of Electron-Rich Arenes

Beatrise Berzina; Igors Sokolovs; Edgars Suna

doi:10.1021/acscatal.5b01992

Copper-Catalyzed para-Selective C-H Amination of Electron-Rich Arenes

Beatrise Berzina
, Igors Sokolovs
, Edgars Suna^*

^*Corresponding author for this work

Latvian Institute of Organic Synthesis

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

A one-pot two-step method for para-selective C-H amination of carbocyclic arenes comprises the in situ formation of unsymmetrical diaryl-λ³-iodanes followed by their Cu(I)-catalyzed reaction with a range of N-unprotected amines.

Original language	English
Pages (from-to)	7008-7014
Number of pages	7
Journal	ACS Catalysis
Volume	5
Issue number	11
DOIs	https://doi.org/10.1021/acscatal.5b01992 https://doi.org/10.1021/acscatal.5b01992
Publication status	Published - 6 Nov 2015
Externally published	Yes

OECD Field of Science

1.4 Chemical Sciences

Keywords

amination
copper
diaryliodonium salts
hypervalent iodine
regioselectivity

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title = "Copper-Catalyzed para-Selective C-H Amination of Electron-Rich Arenes",

abstract = "A one-pot two-step method for para-selective C-H amination of carbocyclic arenes comprises the in situ formation of unsymmetrical diaryl-λ3-iodanes followed by their Cu(I)-catalyzed reaction with a range of N-unprotected amines.",

keywords = "amination, copper, diaryliodonium salts, hypervalent iodine, regioselectivity",

author = "Beatrise Berzina and Igors Sokolovs and Edgars Suna",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = nov,

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doi = "10.1021/acscatal.5b01992",

language = "English",

volume = "5",

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journal = "ACS Catalysis",

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T1 - Copper-Catalyzed para-Selective C-H Amination of Electron-Rich Arenes

AU - Berzina, Beatrise

AU - Sokolovs, Igors

AU - Suna, Edgars

PY - 2015/11/6

Y1 - 2015/11/6

N2 - A one-pot two-step method for para-selective C-H amination of carbocyclic arenes comprises the in situ formation of unsymmetrical diaryl-λ3-iodanes followed by their Cu(I)-catalyzed reaction with a range of N-unprotected amines.

AB - A one-pot two-step method for para-selective C-H amination of carbocyclic arenes comprises the in situ formation of unsymmetrical diaryl-λ3-iodanes followed by their Cu(I)-catalyzed reaction with a range of N-unprotected amines.

KW - amination

KW - copper

KW - diaryliodonium salts

KW - hypervalent iodine

KW - regioselectivity

UR - https://www.scopus.com/pages/publications/84946823984

U2 - 10.1021/acscatal.5b01992

DO - 10.1021/acscatal.5b01992

M3 - Article

AN - SCOPUS:84946823984

SN - 2155-5435

VL - 5

SP - 7008

EP - 7014

JO - ACS Catalysis

JF - ACS Catalysis

IS - 11

ER -

Copper-Catalyzed para-Selective C-H Amination of Electron-Rich Arenes

Abstract

OECD Field of Science

Keywords

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