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Designing highly efficient solvents for the Knoevenagel condensation: Two novel dicationic dimethyl phosphate ionic liquids

  • Elina Priede*
  • , Sindija Brica
  • , Niklavs Udris
  • , Andris Zicmanis
  • *Corresponding author for this work
  • University of Latvia

Research output: Contribution to journalArticlepeer-review

Abstract

Two novel dicationic dimethyl phosphate ionic liquids have been designed as highly efficient solvents for the Knoevenagel condensation between ethyl cyanoacetate and aldehyde with a decreased reactivity - 4-(dimethylamino)benzaldehyde. A simple synthetic strategy has been demonstrated for obtaining the dicationic dimethyl phosphate ionic liquid bearing both aromatic imidazolium and aliphatic ammonium moieties.

Original languageEnglish
Pages (from-to)243-252
Number of pages10
JournalArkivoc
Volume2015
Issue number7
DOIs
Publication statusPublished - 23 Nov 2015

Keywords

  • Anion metathesis
  • Dicationic ionic liquids
  • Dimethyl phosphates
  • Knoevenagel condensation

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