Effect of reagent density fluctuations on bimolecular reaction kinetics

V. N. Kuzovkov; E. A. Kotomin

doi:10.1016/0009-2614(82)83181-3

Effect of reagent density fluctuations on bimolecular reaction kinetics

V. N. Kuzovkov^*
, E. A. Kotomin

^*Corresponding author for this work

Laboratory of Kinetics in Self-Organizing Systems, Institute of Solid State Physics

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The peculiarities of the kinetics of a bimolecular reaction A + B → C caused by non-Poisson fluctuations of reagent densities spontaneously produced during a diffusion-controlled reaction are analysed. The asymptotic long-time kinetics is predicted to be n ∝ t^{- 3 4} (for equal reagent concentrations) contrary to the ordinary law of formal chemical kinetics n ∝ t^-t.

Original language	English
Pages (from-to)	575-578
Number of pages	4
Journal	Chemical Physics Letters
Volume	87
Issue number	6
DOIs	https://doi.org/10.1016/0009-2614(82)83181-3
Publication status	Published - 16 Apr 1982

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10.1016/0009-2614(82)83181-3

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title = "Effect of reagent density fluctuations on bimolecular reaction kinetics",

abstract = "The peculiarities of the kinetics of a bimolecular reaction A + B → C caused by non-Poisson fluctuations of reagent densities spontaneously produced during a diffusion-controlled reaction are analysed. The asymptotic long-time kinetics is predicted to be n ∝ t- 3 4 (for equal reagent concentrations) contrary to the ordinary law of formal chemical kinetics n ∝ t-t.",

author = "Kuzovkov, \{V. N.\} and Kotomin, \{E. A.\}",

year = "1982",

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T1 - Effect of reagent density fluctuations on bimolecular reaction kinetics

AU - Kuzovkov, V. N.

AU - Kotomin, E. A.

PY - 1982/4/16

Y1 - 1982/4/16

N2 - The peculiarities of the kinetics of a bimolecular reaction A + B → C caused by non-Poisson fluctuations of reagent densities spontaneously produced during a diffusion-controlled reaction are analysed. The asymptotic long-time kinetics is predicted to be n ∝ t- 3 4 (for equal reagent concentrations) contrary to the ordinary law of formal chemical kinetics n ∝ t-t.

AB - The peculiarities of the kinetics of a bimolecular reaction A + B → C caused by non-Poisson fluctuations of reagent densities spontaneously produced during a diffusion-controlled reaction are analysed. The asymptotic long-time kinetics is predicted to be n ∝ t- 3 4 (for equal reagent concentrations) contrary to the ordinary law of formal chemical kinetics n ∝ t-t.

UR - https://www.scopus.com/pages/publications/49049132819

U2 - 10.1016/0009-2614(82)83181-3

DO - 10.1016/0009-2614(82)83181-3

M3 - Article

AN - SCOPUS:49049132819

SN - 0009-2614

VL - 87

SP - 575

EP - 578

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 6

ER -

Effect of reagent density fluctuations on bimolecular reaction kinetics

Abstract

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