EXAFS, X-ray diffraction and Raman studies of (Pb1-xLax)(Zr0.65Ti0.35)O3 (x = 0.04 and 0.09) ceramics irradiated by high-current pulsed electron beam

V. V. Efimov; E. A. Efimova; K. Iakoubovskii; S. Khasanov; D. I. Kochubey; V. V. Kriventsov; A. Kuzmin; B. N. Mavrin; M. Sakharov; V. Sikolenko; A. N. Shmakov; S. I. Tiutiunnikov

doi:10.1016/j.jpcs.2006.05.034

EXAFS, X-ray diffraction and Raman studies of (Pb_1-xLa_x)(Zr_0.65Ti_0.35)O₃ (x = 0.04 and 0.09) ceramics irradiated by high-current pulsed electron beam

V. V. Efimov^*
, E. A. Efimova
, K. Iakoubovskii
, S. Khasanov
, D. I. Kochubey
, V. V. Kriventsov
, A. Kuzmin
, B. N. Mavrin
, M. Sakharov
, V. Sikolenko
, A. N. Shmakov
, S. I. Tiutiunnikov

^*Corresponding author for this work

EXAFS Spectroscopy Laboratory, Institute of Solid State Physics

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

We report the effect of pulsed electron beam irradiation on the long-range and short-range atomic structure, as well as on the Raman phonon modes, of perovskite (Pb_1-xLa_x)(Zr_0.65Ti_0.35)O₃, x = 0.04 and 0.09 (PLZT 4/65/35 and 9/65/35) ferroelectric ceramics. X-ray powder diffraction (XRD) spectra from the single-pulse-irradiated PLZT 9/65/35 samples reveal transformation of the cubic Pm3m (Z = 1) into the orthorhombic Pmmm (Z = 1) structure. This symmetry change is however not observed for 10-pulse irradiation performed under the same conditions: here only an increase in the coherent scattering regions, lattice volume, and the Zr-O distance distribution is observed, as revealed by XRD and X-ray absorption spectroscopy at Zr K-edge. Raman scattering from PLZT 9/65/35 ceramics is in agreement with the symmetry reduction after single-pulse irradiation and reveals significant Raman signal intensity decrease after multiple-pulse irradiation. On the contrary, no significant structural changes could be detected in PLZT 4/65/35 ceramics after single- or multiple-pulse irradiation. Possible mechanisms of pulsed electron irradiation effects in PLZT 4/65/35 and 9/65/35 ceramics are discussed.

Original language	English
Pages (from-to)	2007-2012
Number of pages	6
Journal	Journal of Physics and Chemistry of Solids
Volume	67
Issue number	9-10
DOIs	https://doi.org/10.1016/j.jpcs.2006.05.034
Publication status	Published - Sept 2006

Keywords

A. Ceramics
C. Raman spectroscopy
C. X-ray diffraction
C. XAFS (EXAFS and XANES)
D. Defects
D. Radiation damage

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10.1016/j.jpcs.2006.05.034

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Efimov, V. V., Efimova, E. A., Iakoubovskii, K., Khasanov, S., Kochubey, D. I., Kriventsov, V. V., Kuzmin, A., Mavrin, B. N., Sakharov, M., Sikolenko, V., Shmakov, A. N., & Tiutiunnikov, S. I. (2006). EXAFS, X-ray diffraction and Raman studies of (Pb_1-xLa_x)(Zr_0.65Ti_0.35)O₃ (x = 0.04 and 0.09) ceramics irradiated by high-current pulsed electron beam. Journal of Physics and Chemistry of Solids, 67(9-10), 2007-2012. https://doi.org/10.1016/j.jpcs.2006.05.034

@article{d0cf1d74a0604399b4d0c16af2cd2a3c,

title = "EXAFS, X-ray diffraction and Raman studies of (Pb1-xLax)(Zr0.65Ti0.35)O3 (x = 0.04 and 0.09) ceramics irradiated by high-current pulsed electron beam",

abstract = "We report the effect of pulsed electron beam irradiation on the long-range and short-range atomic structure, as well as on the Raman phonon modes, of perovskite (Pb1-xLax)(Zr0.65Ti0.35)O3, x = 0.04 and 0.09 (PLZT 4/65/35 and 9/65/35) ferroelectric ceramics. X-ray powder diffraction (XRD) spectra from the single-pulse-irradiated PLZT 9/65/35 samples reveal transformation of the cubic Pm3m (Z = 1) into the orthorhombic Pmmm (Z = 1) structure. This symmetry change is however not observed for 10-pulse irradiation performed under the same conditions: here only an increase in the coherent scattering regions, lattice volume, and the Zr-O distance distribution is observed, as revealed by XRD and X-ray absorption spectroscopy at Zr K-edge. Raman scattering from PLZT 9/65/35 ceramics is in agreement with the symmetry reduction after single-pulse irradiation and reveals significant Raman signal intensity decrease after multiple-pulse irradiation. On the contrary, no significant structural changes could be detected in PLZT 4/65/35 ceramics after single- or multiple-pulse irradiation. Possible mechanisms of pulsed electron irradiation effects in PLZT 4/65/35 and 9/65/35 ceramics are discussed.",

keywords = "A. Ceramics, C. Raman spectroscopy, C. X-ray diffraction, C. XAFS (EXAFS and XANES), D. Defects, D. Radiation damage",

author = "Efimov, \{V. V.\} and Efimova, \{E. A.\} and K. Iakoubovskii and S. Khasanov and Kochubey, \{D. I.\} and Kriventsov, \{V. V.\} and A. Kuzmin and Mavrin, \{B. N.\} and M. Sakharov and V. Sikolenko and Shmakov, \{A. N.\} and Tiutiunnikov, \{S. I.\}",

year = "2006",

month = sep,

doi = "10.1016/j.jpcs.2006.05.034",

language = "English",

volume = "67",

pages = "2007--2012",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier Ltd",

number = "9-10",

}

Efimov, VV, Efimova, EA, Iakoubovskii, K, Khasanov, S, Kochubey, DI, Kriventsov, VV, Kuzmin, A, Mavrin, BN, Sakharov, M, Sikolenko, V, Shmakov, AN & Tiutiunnikov, SI 2006, 'EXAFS, X-ray diffraction and Raman studies of (Pb_1-xLa_x)(Zr_0.65Ti_0.35)O₃ (x = 0.04 and 0.09) ceramics irradiated by high-current pulsed electron beam', Journal of Physics and Chemistry of Solids, vol. 67, no. 9-10, pp. 2007-2012. https://doi.org/10.1016/j.jpcs.2006.05.034

TY - JOUR

T1 - EXAFS, X-ray diffraction and Raman studies of (Pb1-xLax)(Zr0.65Ti0.35)O3 (x = 0.04 and 0.09) ceramics irradiated by high-current pulsed electron beam

AU - Efimov, V. V.

AU - Efimova, E. A.

AU - Iakoubovskii, K.

AU - Khasanov, S.

AU - Kochubey, D. I.

AU - Kriventsov, V. V.

AU - Kuzmin, A.

AU - Mavrin, B. N.

AU - Sakharov, M.

AU - Sikolenko, V.

AU - Shmakov, A. N.

AU - Tiutiunnikov, S. I.

PY - 2006/9

Y1 - 2006/9

N2 - We report the effect of pulsed electron beam irradiation on the long-range and short-range atomic structure, as well as on the Raman phonon modes, of perovskite (Pb1-xLax)(Zr0.65Ti0.35)O3, x = 0.04 and 0.09 (PLZT 4/65/35 and 9/65/35) ferroelectric ceramics. X-ray powder diffraction (XRD) spectra from the single-pulse-irradiated PLZT 9/65/35 samples reveal transformation of the cubic Pm3m (Z = 1) into the orthorhombic Pmmm (Z = 1) structure. This symmetry change is however not observed for 10-pulse irradiation performed under the same conditions: here only an increase in the coherent scattering regions, lattice volume, and the Zr-O distance distribution is observed, as revealed by XRD and X-ray absorption spectroscopy at Zr K-edge. Raman scattering from PLZT 9/65/35 ceramics is in agreement with the symmetry reduction after single-pulse irradiation and reveals significant Raman signal intensity decrease after multiple-pulse irradiation. On the contrary, no significant structural changes could be detected in PLZT 4/65/35 ceramics after single- or multiple-pulse irradiation. Possible mechanisms of pulsed electron irradiation effects in PLZT 4/65/35 and 9/65/35 ceramics are discussed.

AB - We report the effect of pulsed electron beam irradiation on the long-range and short-range atomic structure, as well as on the Raman phonon modes, of perovskite (Pb1-xLax)(Zr0.65Ti0.35)O3, x = 0.04 and 0.09 (PLZT 4/65/35 and 9/65/35) ferroelectric ceramics. X-ray powder diffraction (XRD) spectra from the single-pulse-irradiated PLZT 9/65/35 samples reveal transformation of the cubic Pm3m (Z = 1) into the orthorhombic Pmmm (Z = 1) structure. This symmetry change is however not observed for 10-pulse irradiation performed under the same conditions: here only an increase in the coherent scattering regions, lattice volume, and the Zr-O distance distribution is observed, as revealed by XRD and X-ray absorption spectroscopy at Zr K-edge. Raman scattering from PLZT 9/65/35 ceramics is in agreement with the symmetry reduction after single-pulse irradiation and reveals significant Raman signal intensity decrease after multiple-pulse irradiation. On the contrary, no significant structural changes could be detected in PLZT 4/65/35 ceramics after single- or multiple-pulse irradiation. Possible mechanisms of pulsed electron irradiation effects in PLZT 4/65/35 and 9/65/35 ceramics are discussed.

KW - A. Ceramics

KW - C. Raman spectroscopy

KW - C. X-ray diffraction

KW - C. XAFS (EXAFS and XANES)

KW - D. Defects

KW - D. Radiation damage

UR - https://www.scopus.com/pages/publications/33748210113

U2 - 10.1016/j.jpcs.2006.05.034

DO - 10.1016/j.jpcs.2006.05.034

M3 - Article

AN - SCOPUS:33748210113

SN - 0022-3697

VL - 67

SP - 2007

EP - 2012

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

IS - 9-10

ER -

EXAFS, X-ray diffraction and Raman studies of (Pb_1-xLa_x)(Zr_0.65Ti_0.35)O₃ (x = 0.04 and 0.09) ceramics irradiated by high-current pulsed electron beam

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Keywords

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