Abstract
In the second chapter of the book the authors present the results of theoretical studies ofthe energy levels schemes of all 3dn (n=1, 9) ionsin various crystals at the substitutionalsites. Systematic calculations are described in all details; they include the overlap integrals between the impurityions' and ligands' wave functions; the crystal field parameters calculations, and diagonalization of the crystal field Hamiltonians for each considered case. The calculated results arediscussed and compared with experimental data and with similar results from literature. The chapter also contains a comprehensive literature review on the properties of 3d-ions doped crystals.
| Original language | English |
|---|---|
| Title of host publication | Optical Properties of 3d-Ions in Crystals |
| Subtitle of host publication | Spectroscopy and Crystal Field Analysis |
| Publisher | Springer-Verlag Berlin Heidelberg |
| Pages | 29-94 |
| Number of pages | 66 |
| ISBN (Electronic) | 9783642308383 |
| ISBN (Print) | 3642308376, 9783642308376 |
| DOIs | |
| Publication status | Published - 1 Aug 2013 |
| Externally published | Yes |
Keywords
- Absorption (spectra, ground state, excited state)
- coordination (octahedral, tetrahedral)
- covalence
- crystal field (parameters, strength, cubic, octahedral, orthorhombic, Hamiltonian)
- crystal lattice
- d-electrons
- energy levels
- exchange charge model
- free ion states
- high and low spin complexes
- Hund rule
- impurity ions
- irreducible tensor operator
- Jahn-Teller (interaction, energy)
- laser materials
- ligand field
- multiples
- nephelauxetic effect
- overlap integral
- Racah parameters
- Stokes shift
- Tanabe-Sugano diagram
- unfilled electron shell
- unit cell
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