Extended x-ray absorption fine structure spectroscopy and first-principles study of SnWO4 [elektronisks resurss]

A. Kuzmin; A. Anspoks; A. Kalinko; J. Timoshenko; R. Kalendarev

doi:10.1088/0031-8949/89/04/044005

Extended x-ray absorption fine structure spectroscopy and first-principles study of SnWO4 [elektronisks resurss]

A. Kuzmin
, A. Anspoks
, A. Kalinko
, J. Timoshenko
, R. Kalendarev

EXAFS Spectroscopy Laboratory, Institute of Solid State Physics

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The local atomic structure in α- and β-SnWO₄ was studied by synchrotron radiation W L₃-edge x-ray absorption spectroscopy at 10 and 300 K. Strongly distorted WO₆ octahedra were found in α-SnWO₄, whereas nearly regular WO₄ tetrahedra were observed in β-SnWO₄, confirming previous results. The structural results obtained were supported by the first-principles calculations, suggesting that the second-order Jahn-Teller effect is responsible for octahedral distortion.

Original language	English
Article number	044005
Journal	Physica Scripta
Volume	89
Issue number	4
DOIs	https://doi.org/10.1088/0031-8949/89/04/044005 https://doi.org/10.1088/0031-8949/89/04/044005
Publication status	Published - Apr 2014

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title = "Extended x-ray absorption fine structure spectroscopy and first-principles study of SnWO4 [elektronisks resurss]",

abstract = "The local atomic structure in α- and β-SnWO4 was studied by synchrotron radiation W L3-edge x-ray absorption spectroscopy at 10 and 300 K. Strongly distorted WO6 octahedra were found in α-SnWO4, whereas nearly regular WO4 tetrahedra were observed in β-SnWO4, confirming previous results. The structural results obtained were supported by the first-principles calculations, suggesting that the second-order Jahn-Teller effect is responsible for octahedral distortion.",

author = "A. Kuzmin and A. Anspoks and A. Kalinko and J. Timoshenko and R. Kalendarev",

year = "2014",

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language = "English",

volume = "89",

journal = "Physica Scripta",

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T1 - Extended x-ray absorption fine structure spectroscopy and first-principles study of SnWO4 [elektronisks resurss]

AU - Kuzmin, A.

AU - Anspoks, A.

AU - Kalinko, A.

AU - Timoshenko, J.

AU - Kalendarev, R.

PY - 2014/4

Y1 - 2014/4

N2 - The local atomic structure in α- and β-SnWO4 was studied by synchrotron radiation W L3-edge x-ray absorption spectroscopy at 10 and 300 K. Strongly distorted WO6 octahedra were found in α-SnWO4, whereas nearly regular WO4 tetrahedra were observed in β-SnWO4, confirming previous results. The structural results obtained were supported by the first-principles calculations, suggesting that the second-order Jahn-Teller effect is responsible for octahedral distortion.

AB - The local atomic structure in α- and β-SnWO4 was studied by synchrotron radiation W L3-edge x-ray absorption spectroscopy at 10 and 300 K. Strongly distorted WO6 octahedra were found in α-SnWO4, whereas nearly regular WO4 tetrahedra were observed in β-SnWO4, confirming previous results. The structural results obtained were supported by the first-principles calculations, suggesting that the second-order Jahn-Teller effect is responsible for octahedral distortion.

UR - https://www.scopus.com/pages/publications/84897375170

U2 - 10.1088/0031-8949/89/04/044005

DO - 10.1088/0031-8949/89/04/044005

M3 - Article

AN - SCOPUS:84897375170

SN - 0031-8949

VL - 89

JO - Physica Scripta

JF - Physica Scripta

IS - 4

M1 - 044005

ER -

Extended x-ray absorption fine structure spectroscopy and first-principles study of SnWO4 [elektronisks resurss]

Abstract

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