Functional energy accumulation, photo- And magnetosensitive hybridity in the GaSe-based hierarchical structures

Piotr Chabecki; Dariusz Całus; Fedir Ivashchyshyn; Anna Pidluzhna; Orest Hryhorchak; Ihor Bordun; Oleksandr Makarchuk; Andriy V. Kityk

doi:10.3390/en13174321

Functional energy accumulation, photo- And magnetosensitive hybridity in the GaSe-based hierarchical structures

Piotr Chabecki
, Dariusz Całus
, Fedir Ivashchyshyn
, Anna Pidluzhna
, Orest Hryhorchak
, Ihor Bordun
, Oleksandr Makarchuk
, Andriy V. Kityk^*

^*Corresponding author for this work

Częstochowa University of Technology
Lviv Polytechnic National University
Ivan Franko National University of L'viv

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

We report on the complex GaSe-based hierarchical structures GaSe(CS(NH₂)₂), GaSe(SmCl₃) and GaSe(CS(NH₂)₂(SmCl₃)) synthesized by an intercalation method. The conductive properties of synthesized clathrates and their relation to hierarchical structural complexity were explored by an impedance spectroscopy technique. The impedance response, thermostimulated discharge spectra, and photo- and magnetoresistive effects are reported. Based on the obtained results, the impurity energy spectra were calculated. A strong low-frequency inductive response, observable in the GaSe(SmCl₃) clathrate, makes this material promising for the development of gyrator-free nanodelay lines potentially applicable in nanoelectronics. Hierarchical GaSe(CS(NH₂)₂(SmCl₃)) clathrate, on the other hand, reveals hysteresis of the current–voltage characteristics, apparently confirming an accumulation of electric energy at interphase boundaries. A relevant spin battery effect, observable experimentally in stationary magnetic fields, demonstrates a principal possibility of the electric energy accumulation at a quantum level.

Original language	English
Article number	4321
Journal	Energies
Volume	13
Issue number	17
DOIs	https://doi.org/10.3390/en13174321
Publication status	Published - Sept 2020
Externally published	Yes

Keywords

Hierarchical architecture
Impedance spectroscopy
Magnetoresistivity
Photoresistivity
Spin battery effect
Supramolecular ensemble

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title = "Functional energy accumulation, photo- And magnetosensitive hybridity in the GaSe-based hierarchical structures",

abstract = "We report on the complex GaSe-based hierarchical structures GaSe(CS(NH2)2), GaSe(SmCl3) and GaSe(CS(NH2)2(SmCl3)) synthesized by an intercalation method. The conductive properties of synthesized clathrates and their relation to hierarchical structural complexity were explored by an impedance spectroscopy technique. The impedance response, thermostimulated discharge spectra, and photo- and magnetoresistive effects are reported. Based on the obtained results, the impurity energy spectra were calculated. A strong low-frequency inductive response, observable in the GaSe(SmCl3) clathrate, makes this material promising for the development of gyrator-free nanodelay lines potentially applicable in nanoelectronics. Hierarchical GaSe(CS(NH2)2(SmCl3)) clathrate, on the other hand, reveals hysteresis of the current–voltage characteristics, apparently confirming an accumulation of electric energy at interphase boundaries. A relevant spin battery effect, observable experimentally in stationary magnetic fields, demonstrates a principal possibility of the electric energy accumulation at a quantum level.",

keywords = "Hierarchical architecture, Impedance spectroscopy, Magnetoresistivity, Photoresistivity, Spin battery effect, Supramolecular ensemble",

author = "Piotr Chabecki and Dariusz Ca{\l}us and Fedir Ivashchyshyn and Anna Pidluzhna and Orest Hryhorchak and Ihor Bordun and Oleksandr Makarchuk and Kityk, \{Andriy V.\}",

note = "Publisher Copyright: {\textcopyright} 2020 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2020",

month = sep,

doi = "10.3390/en13174321",

language = "English",

volume = "13",

journal = "Energies",

issn = "1996-1073",

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TY - JOUR

T1 - Functional energy accumulation, photo- And magnetosensitive hybridity in the GaSe-based hierarchical structures

AU - Chabecki, Piotr

AU - Całus, Dariusz

AU - Ivashchyshyn, Fedir

AU - Pidluzhna, Anna

AU - Hryhorchak, Orest

AU - Bordun, Ihor

AU - Makarchuk, Oleksandr

AU - Kityk, Andriy V.

PY - 2020/9

Y1 - 2020/9

N2 - We report on the complex GaSe-based hierarchical structures GaSe(CS(NH2)2), GaSe(SmCl3) and GaSe(CS(NH2)2(SmCl3)) synthesized by an intercalation method. The conductive properties of synthesized clathrates and their relation to hierarchical structural complexity were explored by an impedance spectroscopy technique. The impedance response, thermostimulated discharge spectra, and photo- and magnetoresistive effects are reported. Based on the obtained results, the impurity energy spectra were calculated. A strong low-frequency inductive response, observable in the GaSe(SmCl3) clathrate, makes this material promising for the development of gyrator-free nanodelay lines potentially applicable in nanoelectronics. Hierarchical GaSe(CS(NH2)2(SmCl3)) clathrate, on the other hand, reveals hysteresis of the current–voltage characteristics, apparently confirming an accumulation of electric energy at interphase boundaries. A relevant spin battery effect, observable experimentally in stationary magnetic fields, demonstrates a principal possibility of the electric energy accumulation at a quantum level.

AB - We report on the complex GaSe-based hierarchical structures GaSe(CS(NH2)2), GaSe(SmCl3) and GaSe(CS(NH2)2(SmCl3)) synthesized by an intercalation method. The conductive properties of synthesized clathrates and their relation to hierarchical structural complexity were explored by an impedance spectroscopy technique. The impedance response, thermostimulated discharge spectra, and photo- and magnetoresistive effects are reported. Based on the obtained results, the impurity energy spectra were calculated. A strong low-frequency inductive response, observable in the GaSe(SmCl3) clathrate, makes this material promising for the development of gyrator-free nanodelay lines potentially applicable in nanoelectronics. Hierarchical GaSe(CS(NH2)2(SmCl3)) clathrate, on the other hand, reveals hysteresis of the current–voltage characteristics, apparently confirming an accumulation of electric energy at interphase boundaries. A relevant spin battery effect, observable experimentally in stationary magnetic fields, demonstrates a principal possibility of the electric energy accumulation at a quantum level.

KW - Hierarchical architecture

KW - Impedance spectroscopy

KW - Magnetoresistivity

KW - Photoresistivity

KW - Spin battery effect

KW - Supramolecular ensemble

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U2 - 10.3390/en13174321

DO - 10.3390/en13174321

M3 - Article

AN - SCOPUS:85090427051

SN - 1996-1073

VL - 13

JO - Energies

JF - Energies

IS - 17

M1 - 4321

ER -

Functional energy accumulation, photo- And magnetosensitive hybridity in the GaSe-based hierarchical structures

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Keywords

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