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In-situ x-ray absorption fine structure and x-ray diffraction studies of hydrogen intercalation in tungsten oxides

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Abstract

We present in-situ x-ray absorption fine structure (XAFS) (at the W L 3-edge) and x-ray diffraction (XRD) studies of hydrogen intercalation into stable monoclinic (m-WO3) and metastable hexagonal (h-WO 3) and cubic (c-WO3) phases of tungsten oxide. The analysis of XAFS and XRD data allowed us to reconstruct the local environment around tungsten ions in the first coordination shell. The obtained results are compared with the existing structural models.

Original languageEnglish
Pages (from-to)174-179
Number of pages6
JournalProceedings of SPIE - The International Society for Optical Engineering
Volume2968
DOIs
Publication statusPublished - 1997
EventOptical Organic and Semiconductor Inorganic Materials - Riga, Latvia
Duration: 26 Aug 199626 Aug 1996

Keywords

  • Hydrogen intercalation
  • Structure
  • Tungsten oxides
  • XAFS
  • XRD

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