Influence of the scaling inhibitor on the phase composition, morphology, and sedimentation properties of caco3 deposits

V. B. Obraztsov; E. D. Rubl’Ova; O. S. Baskevych

doi:10.1007/s11003-016-9887-3

Influence of the scaling inhibitor on the phase composition, morphology, and sedimentation properties of caco₃ deposits

V. B. Obraztsov
, E. D. Rubl’Ova^*
, O. S. Baskevych

^*Corresponding author for this work

Ukrainian State Chemicotechnological University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

We study the influence of OK-2 scaling inhibitor based on polyhexamethyleneguanidine hydrochloride on the morphology and phase composition of calcium carbonate. It is established that the presence of inhibitor in the solution leads to an increase in the sizes of crystals in the deposit and the predominance of needle structures in it. The aragonite and calcite phases are in excess in the deposits of calcium carbonate and the presence of inhibitor in the solution increases the amount of calcite by 21%. The revealed effects are caused by the adsorption of the inhibitor on carbonate deposits, which can be described by the Langmuir isotherm. The adsorption of the inhibitor leads to the recharging of the CaCO₃ surface and to the increase in the size of particles of the dispersed phase, which promotes its faster precipitation.

Original language	English
Pages (from-to)	652-658
Number of pages	7
Journal	Materials Science
Volume	51
Issue number	5
DOIs	https://doi.org/10.1007/s11003-016-9887-3
Publication status	Published - Mar 2016
Externally published	Yes

Keywords

Adsorption
Calcium carbonate
Morphology
Sedimentation

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10.1007/s11003-016-9887-3

Cite this

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title = "Influence of the scaling inhibitor on the phase composition, morphology, and sedimentation properties of caco3 deposits",

abstract = "We study the influence of OK-2 scaling inhibitor based on polyhexamethyleneguanidine hydrochloride on the morphology and phase composition of calcium carbonate. It is established that the presence of inhibitor in the solution leads to an increase in the sizes of crystals in the deposit and the predominance of needle structures in it. The aragonite and calcite phases are in excess in the deposits of calcium carbonate and the presence of inhibitor in the solution increases the amount of calcite by 21\%. The revealed effects are caused by the adsorption of the inhibitor on carbonate deposits, which can be described by the Langmuir isotherm. The adsorption of the inhibitor leads to the recharging of the CaCO3 surface and to the increase in the size of particles of the dispersed phase, which promotes its faster precipitation.",

keywords = "Adsorption, Calcium carbonate, Morphology, Sedimentation",

author = "Obraztsov, \{V. B.\} and Rubl{\textquoteright}Ova, \{E. D.\} and Baskevych, \{O. S.\}",

note = "Publisher Copyright: {\textcopyright} 2016 Springer Science+Business Media New York.",

year = "2016",

month = mar,

doi = "10.1007/s11003-016-9887-3",

language = "English",

volume = "51",

pages = "652--658",

journal = "Materials Science",

issn = "1068-820X",

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number = "5",

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T1 - Influence of the scaling inhibitor on the phase composition, morphology, and sedimentation properties of caco3 deposits

AU - Obraztsov, V. B.

AU - Rubl’Ova, E. D.

AU - Baskevych, O. S.

PY - 2016/3

Y1 - 2016/3

N2 - We study the influence of OK-2 scaling inhibitor based on polyhexamethyleneguanidine hydrochloride on the morphology and phase composition of calcium carbonate. It is established that the presence of inhibitor in the solution leads to an increase in the sizes of crystals in the deposit and the predominance of needle structures in it. The aragonite and calcite phases are in excess in the deposits of calcium carbonate and the presence of inhibitor in the solution increases the amount of calcite by 21%. The revealed effects are caused by the adsorption of the inhibitor on carbonate deposits, which can be described by the Langmuir isotherm. The adsorption of the inhibitor leads to the recharging of the CaCO3 surface and to the increase in the size of particles of the dispersed phase, which promotes its faster precipitation.

AB - We study the influence of OK-2 scaling inhibitor based on polyhexamethyleneguanidine hydrochloride on the morphology and phase composition of calcium carbonate. It is established that the presence of inhibitor in the solution leads to an increase in the sizes of crystals in the deposit and the predominance of needle structures in it. The aragonite and calcite phases are in excess in the deposits of calcium carbonate and the presence of inhibitor in the solution increases the amount of calcite by 21%. The revealed effects are caused by the adsorption of the inhibitor on carbonate deposits, which can be described by the Langmuir isotherm. The adsorption of the inhibitor leads to the recharging of the CaCO3 surface and to the increase in the size of particles of the dispersed phase, which promotes its faster precipitation.

KW - Adsorption

KW - Calcium carbonate

KW - Morphology

KW - Sedimentation

UR - https://www.scopus.com/pages/publications/85047533419

U2 - 10.1007/s11003-016-9887-3

DO - 10.1007/s11003-016-9887-3

M3 - Article

AN - SCOPUS:85047533419

SN - 1068-820X

VL - 51

SP - 652

EP - 658

JO - Materials Science

JF - Materials Science

IS - 5

ER -

Influence of the scaling inhibitor on the phase composition, morphology, and sedimentation properties of caco₃ deposits

Abstract

Keywords

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