Interference blockage of electron tunneling and pseudo-Faraday hypercapacity for C-SiO 2 nanocomposites

I. I. Grygorchak; B. A. Lukiyanets; A. Yu Pidluzhna; D. V. Matulka; I. F. Myronyuk

doi:10.1134/S0036024412010116

Interference blockage of electron tunneling and pseudo-Faraday hypercapacity for C-SiO ₂ nanocomposites

I. I. Grygorchak^*
, B. A. Lukiyanets
, A. Yu Pidluzhna
, D. V. Matulka
, I. F. Myronyuk

^*Corresponding author for this work

Lviv Polytechnic National University
Vasyl Stefanyk Precarpathian National University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The thermodynamic and kinetic regularities of the intercalation of lithium into C-SiO ₂ nanocomposites are studied. The dependence of the differential capacity and kinetic intercalation parameters on the size of nanocomposite particles is established. According to theoretical analysis, the obtained results are explained as resulting from the quantum-mechanical effect of the interference blockage of the tunneling of an electron into a nonmetallic nanoparticle. An impedance model of processes and its parametric identification are given. A new class of electrochemical energy generators is proposed.

Original language	English
Pages (from-to)	100-105
Number of pages	6
Journal	Russian Journal of Physical Chemistry A
Volume	86
Issue number	1
DOIs	https://doi.org/10.1134/S0036024412010116
Publication status	Published - Jan 2012
Externally published	Yes

Keywords

intercalation
interference blockage
nanocomposite
tunneling

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abstract = "The thermodynamic and kinetic regularities of the intercalation of lithium into C-SiO 2 nanocomposites are studied. The dependence of the differential capacity and kinetic intercalation parameters on the size of nanocomposite particles is established. According to theoretical analysis, the obtained results are explained as resulting from the quantum-mechanical effect of the interference blockage of the tunneling of an electron into a nonmetallic nanoparticle. An impedance model of processes and its parametric identification are given. A new class of electrochemical energy generators is proposed.",

keywords = "intercalation, interference blockage, nanocomposite, tunneling",

author = "Grygorchak, \{I. I.\} and Lukiyanets, \{B. A.\} and Pidluzhna, \{A. Yu\} and Matulka, \{D. V.\} and Myronyuk, \{I. F.\}",

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AU - Grygorchak, I. I.

AU - Lukiyanets, B. A.

AU - Pidluzhna, A. Yu

AU - Matulka, D. V.

AU - Myronyuk, I. F.

PY - 2012/1

Y1 - 2012/1

N2 - The thermodynamic and kinetic regularities of the intercalation of lithium into C-SiO 2 nanocomposites are studied. The dependence of the differential capacity and kinetic intercalation parameters on the size of nanocomposite particles is established. According to theoretical analysis, the obtained results are explained as resulting from the quantum-mechanical effect of the interference blockage of the tunneling of an electron into a nonmetallic nanoparticle. An impedance model of processes and its parametric identification are given. A new class of electrochemical energy generators is proposed.

AB - The thermodynamic and kinetic regularities of the intercalation of lithium into C-SiO 2 nanocomposites are studied. The dependence of the differential capacity and kinetic intercalation parameters on the size of nanocomposite particles is established. According to theoretical analysis, the obtained results are explained as resulting from the quantum-mechanical effect of the interference blockage of the tunneling of an electron into a nonmetallic nanoparticle. An impedance model of processes and its parametric identification are given. A new class of electrochemical energy generators is proposed.

KW - intercalation

KW - interference blockage

KW - nanocomposite

KW - tunneling

UR - https://www.scopus.com/pages/publications/84856303563

U2 - 10.1134/S0036024412010116

DO - 10.1134/S0036024412010116

M3 - Article

AN - SCOPUS:84856303563

SN - 0036-0244

VL - 86

SP - 100

EP - 105

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

IS - 1

ER -

Interference blockage of electron tunneling and pseudo-Faraday hypercapacity for C-SiO ₂ nanocomposites

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Keywords

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