Luminescence and energy transfer of Ce3+, Eu2+ co-doped Ba2Mg(BO3)2 for potential anti-counterfeiting applications

Quanfeng Li; Yiyi Ou; Yunlin Yang; Jianhui Zhang; Mikhail G. Brik; Hongbin Liang

doi:10.1016/j.jlumin.2022.119564

Luminescence and energy transfer of Ce³⁺, Eu²⁺ co-doped Ba₂Mg(BO₃)₂ for potential anti-counterfeiting applications

Quanfeng Li
, Yiyi Ou
, Yunlin Yang
, Jianhui Zhang
, Mikhail G. Brik
, Hongbin Liang^*

^*Corresponding author for this work

Sun Yat-Sen University
Chongqing University of Posts and Telecommunications
University of Tartu
Jan Dlugosz University in Czestochowa
Academy of Romanian Scientists

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The phosphors Ba₂Mg(BO₃)₂ activated with Ce³⁺ and Eu²⁺ ions are prepared by a solid-state reaction method at high-temperature and the Rietveld structure refinement of the host compound is performed. The synchrotron radiation VUV - UV excitation, UV – vis emission and luminescence decay spectra, as well as the dependencies of luminescence intensity and lifetime on doping content and temperature are systematically investigated. In addition, the electron-vibrational interaction (EVI) of Eu²⁺ ions with coordination surroundings and the Ce³⁺→Eu²⁺ energy transfer (ET) dynamics are studied in detail. Based on above discussion, the potential applications of co-doped phosphors in excitation wavelength and temperature dual-response optical anti-counterfeiting are demonstrated.

Original language	English
Article number	119564
Journal	Journal of Luminescence
Volume	255
DOIs	https://doi.org/10.1016/j.jlumin.2022.119564
Publication status	Published - Mar 2023
Externally published	Yes

Keywords

BaMg(BO)
Ce
Eu
Luminescence
Optical anti-counterfeiting

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10.1016/j.jlumin.2022.119564

Cite this

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title = "Luminescence and energy transfer of Ce3+, Eu2+ co-doped Ba2Mg(BO3)2 for potential anti-counterfeiting applications",

abstract = "The phosphors Ba2Mg(BO3)2 activated with Ce3+ and Eu2+ ions are prepared by a solid-state reaction method at high-temperature and the Rietveld structure refinement of the host compound is performed. The synchrotron radiation VUV - UV excitation, UV – vis emission and luminescence decay spectra, as well as the dependencies of luminescence intensity and lifetime on doping content and temperature are systematically investigated. In addition, the electron-vibrational interaction (EVI) of Eu2+ ions with coordination surroundings and the Ce3+→Eu2+ energy transfer (ET) dynamics are studied in detail. Based on above discussion, the potential applications of co-doped phosphors in excitation wavelength and temperature dual-response optical anti-counterfeiting are demonstrated.",

keywords = "BaMg(BO), Ce, Eu, Luminescence, Optical anti-counterfeiting",

author = "Quanfeng Li and Yiyi Ou and Yunlin Yang and Jianhui Zhang and Brik, \{Mikhail G.\} and Hongbin Liang",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2023",

month = mar,

doi = "10.1016/j.jlumin.2022.119564",

language = "English",

volume = "255",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Luminescence and energy transfer of Ce3+, Eu2+ co-doped Ba2Mg(BO3)2 for potential anti-counterfeiting applications

AU - Li, Quanfeng

AU - Ou, Yiyi

AU - Yang, Yunlin

AU - Zhang, Jianhui

AU - Brik, Mikhail G.

AU - Liang, Hongbin

PY - 2023/3

Y1 - 2023/3

N2 - The phosphors Ba2Mg(BO3)2 activated with Ce3+ and Eu2+ ions are prepared by a solid-state reaction method at high-temperature and the Rietveld structure refinement of the host compound is performed. The synchrotron radiation VUV - UV excitation, UV – vis emission and luminescence decay spectra, as well as the dependencies of luminescence intensity and lifetime on doping content and temperature are systematically investigated. In addition, the electron-vibrational interaction (EVI) of Eu2+ ions with coordination surroundings and the Ce3+→Eu2+ energy transfer (ET) dynamics are studied in detail. Based on above discussion, the potential applications of co-doped phosphors in excitation wavelength and temperature dual-response optical anti-counterfeiting are demonstrated.

AB - The phosphors Ba2Mg(BO3)2 activated with Ce3+ and Eu2+ ions are prepared by a solid-state reaction method at high-temperature and the Rietveld structure refinement of the host compound is performed. The synchrotron radiation VUV - UV excitation, UV – vis emission and luminescence decay spectra, as well as the dependencies of luminescence intensity and lifetime on doping content and temperature are systematically investigated. In addition, the electron-vibrational interaction (EVI) of Eu2+ ions with coordination surroundings and the Ce3+→Eu2+ energy transfer (ET) dynamics are studied in detail. Based on above discussion, the potential applications of co-doped phosphors in excitation wavelength and temperature dual-response optical anti-counterfeiting are demonstrated.

KW - BaMg(BO)

KW - Ce

KW - Eu

KW - Luminescence

KW - Optical anti-counterfeiting

UR - https://www.scopus.com/pages/publications/85143859522

U2 - 10.1016/j.jlumin.2022.119564

DO - 10.1016/j.jlumin.2022.119564

M3 - Article

AN - SCOPUS:85143859522

SN - 0022-2313

VL - 255

JO - Journal of Luminescence

JF - Journal of Luminescence

M1 - 119564

ER -

Luminescence and energy transfer of Ce³⁺, Eu²⁺ co-doped Ba₂Mg(BO₃)₂ for potential anti-counterfeiting applications

Abstract

Keywords

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