Mechanism of Q(C≡N) band broadening in condensed state of alkoxycyanobiphenyles

V. Krasnoholovets; I. Khakimov; G. Puchkovskaya; E. Gabrusenoks

doi:10.1080/10587250008024799

Mechanism of Q(C≡N) band broadening in condensed state of alkoxycyanobiphenyles

V. Krasnoholovets^*
, I. Khakimov
, G. Puchkovskaya
, E. Gabrusenoks

^*Corresponding author for this work

National Academy of Sciences of Ukraine
Riga Stradins University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the present paper the spectral-structural-phase correlations in a series of the 4-cyano-4′-n-alkoxybiphenyles (n = 3 - 8) are studied. The analysis of Q(C≡N) band behaviour in the solid crystal (SC), liquid crystal (LC), isotropic liquid (IL) and hexane solution is carried out. The mechanism of intradimer energy transfer which explains the Q(C≡N) band breadth in the LC and IL phases is proposed.

Original language	English
Pages (from-to)	101-109
Number of pages	9
Journal	Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals
Volume	348
DOIs	https://doi.org/10.1080/10587250008024799
Publication status	Published - 2000
Externally published	Yes

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abstract = "In the present paper the spectral-structural-phase correlations in a series of the 4-cyano-4′-n-alkoxybiphenyles (n = 3 - 8) are studied. The analysis of Q(C≡N) band behaviour in the solid crystal (SC), liquid crystal (LC), isotropic liquid (IL) and hexane solution is carried out. The mechanism of intradimer energy transfer which explains the Q(C≡N) band breadth in the LC and IL phases is proposed.",

author = "V. Krasnoholovets and I. Khakimov and G. Puchkovskaya and E. Gabrusenoks",

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AU - Krasnoholovets, V.

AU - Khakimov, I.

AU - Puchkovskaya, G.

AU - Gabrusenoks, E.

PY - 2000

Y1 - 2000

N2 - In the present paper the spectral-structural-phase correlations in a series of the 4-cyano-4′-n-alkoxybiphenyles (n = 3 - 8) are studied. The analysis of Q(C≡N) band behaviour in the solid crystal (SC), liquid crystal (LC), isotropic liquid (IL) and hexane solution is carried out. The mechanism of intradimer energy transfer which explains the Q(C≡N) band breadth in the LC and IL phases is proposed.

AB - In the present paper the spectral-structural-phase correlations in a series of the 4-cyano-4′-n-alkoxybiphenyles (n = 3 - 8) are studied. The analysis of Q(C≡N) band behaviour in the solid crystal (SC), liquid crystal (LC), isotropic liquid (IL) and hexane solution is carried out. The mechanism of intradimer energy transfer which explains the Q(C≡N) band breadth in the LC and IL phases is proposed.

UR - https://www.scopus.com/pages/publications/0034479829

U2 - 10.1080/10587250008024799

DO - 10.1080/10587250008024799

M3 - Article

AN - SCOPUS:0034479829

SN - 1058-725X

VL - 348

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JO - Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals

ER -

Mechanism of Q(C≡N) band broadening in condensed state of alkoxycyanobiphenyles

Abstract

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