New approach to the EPR of d1 ions in glasses

A. Bals; J. Kliava; J. Purans

doi:10.1088/0022-3719/13/17/001

New approach to the EPR of d¹ ions in glasses

A. Bals^*
, J. Kliava
, J. Purans

^*Corresponding author for this work

Thin Films Laboratory, Institute of Solid State Physics

University of Latvia

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The EPR spectra of d¹ ions in glasses are computer simulated taking into account distributions of the components of the g tensor resulting from the structural disorder. By fitting to the experimental spectrum for Mo⁵⁺ ions in BaO-P₂O₅ glass, the following mean values of the spin Hamiltonian parameters are obtained: g_x0=1.941, g_y0=1.923, g_z0=1.888. The corresponding distribution widths are: Delta g_x=0.0077; Delta g_y=0.0067; Delta sig_z=0.0084. From these values, the authors estimate that the random variations of Mo-O distances in glass are about 1%.

Original language	English
Article number	001
Pages (from-to)	L437-L441
Journal	Journal of Physics C: Solid State Physics
Volume	13
Issue number	17
DOIs	https://doi.org/10.1088/0022-3719/13/17/001
Publication status	Published - 1980

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title = "New approach to the EPR of d1 ions in glasses",

abstract = "The EPR spectra of d1 ions in glasses are computer simulated taking into account distributions of the components of the g tensor resulting from the structural disorder. By fitting to the experimental spectrum for Mo5+ ions in BaO-P2O5 glass, the following mean values of the spin Hamiltonian parameters are obtained: gx0=1.941, gy0=1.923, gz0=1.888. The corresponding distribution widths are: Delta gx=0.0077; Delta gy=0.0067; Delta sigz=0.0084. From these values, the authors estimate that the random variations of Mo-O distances in glass are about 1\%.",

author = "A. Bals and J. Kliava and J. Purans",

year = "1980",

doi = "10.1088/0022-3719/13/17/001",

language = "English",

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pages = "L437--L441",

journal = "Journal of Physics C: Solid State Physics",

issn = "0022-3719",

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number = "17",

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TY - JOUR

T1 - New approach to the EPR of d1 ions in glasses

AU - Bals, A.

AU - Kliava, J.

AU - Purans, J.

PY - 1980

Y1 - 1980

N2 - The EPR spectra of d1 ions in glasses are computer simulated taking into account distributions of the components of the g tensor resulting from the structural disorder. By fitting to the experimental spectrum for Mo5+ ions in BaO-P2O5 glass, the following mean values of the spin Hamiltonian parameters are obtained: gx0=1.941, gy0=1.923, gz0=1.888. The corresponding distribution widths are: Delta gx=0.0077; Delta gy=0.0067; Delta sigz=0.0084. From these values, the authors estimate that the random variations of Mo-O distances in glass are about 1%.

AB - The EPR spectra of d1 ions in glasses are computer simulated taking into account distributions of the components of the g tensor resulting from the structural disorder. By fitting to the experimental spectrum for Mo5+ ions in BaO-P2O5 glass, the following mean values of the spin Hamiltonian parameters are obtained: gx0=1.941, gy0=1.923, gz0=1.888. The corresponding distribution widths are: Delta gx=0.0077; Delta gy=0.0067; Delta sigz=0.0084. From these values, the authors estimate that the random variations of Mo-O distances in glass are about 1%.

UR - https://www.scopus.com/pages/publications/4244141836

U2 - 10.1088/0022-3719/13/17/001

DO - 10.1088/0022-3719/13/17/001

M3 - Article

AN - SCOPUS:4244141836

SN - 0022-3719

VL - 13

SP - L437-L441

JO - Journal of Physics C: Solid State Physics

JF - Journal of Physics C: Solid State Physics

IS - 17

M1 - 001

ER -

New approach to the EPR of d¹ ions in glasses

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