New figure of merit for tailoring optimal structure of the second order NLO chromophore for guest-host polymers

M. Rutkis; A. Jurgis; V. Kampars; A. Vembris; A. Tokmakovs; V. Kokars

doi:10.1080/15421400801924847

New figure of merit for tailoring optimal structure of the second order NLO chromophore for guest-host polymers

M. Rutkis^*
, A. Jurgis
, V. Kampars
, A. Vembris
, A. Tokmakovs
, V. Kokars

^*Corresponding author for this work

Institute of Electronics and Computer Science
Riga Technical University

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Reliability to forecast SHG efficiency using two sets of non linear optical (NLO) chromophore figures of merit (FOM) was tested. One of them predicts that SHG efficiency d33 of the poled guest-host polymer is proportional to ground state dipoleg, another to1/g. Correlation of maximal achieved second order NLO efficiency of the PMMA based systems containing eight dimethylaminobenzylidene- 1, 3-indandione (DMABI) related chromophores with proposed FOM have been analyzed. The best correlations were obtained with second set of FOM, especially if high dipole moment (g7D) chromophores are included in analysis.

Original language	English
Pages (from-to)	903-914
Number of pages	12
Journal	Molecular Crystals and Liquid Crystals
Volume	485
DOIs	https://doi.org/10.1080/15421400801924847
Publication status	Published - 2008

Keywords

Figure of merit
Guest-host polymers
NLO chromophores
SHG efficiency

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10.1080/15421400801924847

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title = "New figure of merit for tailoring optimal structure of the second order NLO chromophore for guest-host polymers",

abstract = "Reliability to forecast SHG efficiency using two sets of non linear optical (NLO) chromophore figures of merit (FOM) was tested. One of them predicts that SHG efficiency d33 of the poled guest-host polymer is proportional to ground state dipoleg, another to1/g. Correlation of maximal achieved second order NLO efficiency of the PMMA based systems containing eight dimethylaminobenzylidene- 1, 3-indandione (DMABI) related chromophores with proposed FOM have been analyzed. The best correlations were obtained with second set of FOM, especially if high dipole moment (g7D) chromophores are included in analysis.",

keywords = "Figure of merit, Guest-host polymers, NLO chromophores, SHG efficiency",

author = "M. Rutkis and A. Jurgis and V. Kampars and A. Vembris and A. Tokmakovs and V. Kokars",

year = "2008",

doi = "10.1080/15421400801924847",

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TY - JOUR

T1 - New figure of merit for tailoring optimal structure of the second order NLO chromophore for guest-host polymers

AU - Rutkis, M.

AU - Jurgis, A.

AU - Kampars, V.

AU - Vembris, A.

AU - Tokmakovs, A.

AU - Kokars, V.

PY - 2008

Y1 - 2008

N2 - Reliability to forecast SHG efficiency using two sets of non linear optical (NLO) chromophore figures of merit (FOM) was tested. One of them predicts that SHG efficiency d33 of the poled guest-host polymer is proportional to ground state dipoleg, another to1/g. Correlation of maximal achieved second order NLO efficiency of the PMMA based systems containing eight dimethylaminobenzylidene- 1, 3-indandione (DMABI) related chromophores with proposed FOM have been analyzed. The best correlations were obtained with second set of FOM, especially if high dipole moment (g7D) chromophores are included in analysis.

AB - Reliability to forecast SHG efficiency using two sets of non linear optical (NLO) chromophore figures of merit (FOM) was tested. One of them predicts that SHG efficiency d33 of the poled guest-host polymer is proportional to ground state dipoleg, another to1/g. Correlation of maximal achieved second order NLO efficiency of the PMMA based systems containing eight dimethylaminobenzylidene- 1, 3-indandione (DMABI) related chromophores with proposed FOM have been analyzed. The best correlations were obtained with second set of FOM, especially if high dipole moment (g7D) chromophores are included in analysis.

KW - Figure of merit

KW - Guest-host polymers

KW - NLO chromophores

KW - SHG efficiency

UR - https://www.scopus.com/pages/publications/47549111936

U2 - 10.1080/15421400801924847

DO - 10.1080/15421400801924847

M3 - Article

AN - SCOPUS:47549111936

SN - 1542-1406

VL - 485

SP - 903

EP - 914

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

ER -

New figure of merit for tailoring optimal structure of the second order NLO chromophore for guest-host polymers

Abstract

Keywords

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