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Partially graphitic nanoporous activated carbon prepared from biomass for supercapacitor application

  • Sivagaami Sundari Gunasekaran
  • , Senthil Kumar Elumalali
  • , Thileep Kumar Kumaresan
  • , Ramya Meganathan
  • , Ashwini Ashok
  • , Varsha Pawar
  • , Kumaran Vediappan
  • , Gnanamuthu Ramasamy
  • , Smagul Zh Karazhanov
  • , Kalaivani Raman*
  • , Raghu Subashchandra Bose
  • *Corresponding author for this work
  • Vels Institute of Science, Technology & Advanced Studies
  • SRM Institute of Science and Technology
  • Institute for Energy Technology

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

In this present work, the preparation of partially graphitic nanoporous carbon from biomass (bamboo bagasse) is carried out using potassium ferrocyanide and -KOH as activating agent with controlled temperature and gas flow rates. The physico-chemical properties of biomass-derived graphitic nano-porous carbon were characterized by X-ray Diffraction (XRD), Fourier Transform Infra-Red Spectroscopy (FTIR), Thermal Gravimetric Analysis (TGA), Raman spectroscopy, Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and electrochemical measurements. It is interesting that the activation with the iron salts plays a significant role in the formation of graphitic structures. The graphitic nanoporous carbonaceous materials show high specific surface area of 1360 m2 g−1, low impedance, large pore volume and high specific capacitance. Thus, the iron-catalyzed graphitic carbon is excellent candidate for the supercapacitor applications. This contemporary- novel method to synthesis of nanoporous carbon represents a great potential for apparent and diversified applications in energy storage materials.

Original languageEnglish
Pages (from-to)165-168
Number of pages4
JournalMaterials Letters
Volume218
DOIs
Publication statusPublished - 1 May 2018
Externally publishedYes

Keywords

  • Carbonization
  • Energy storage materials
  • Graphene
  • Supercapacitor

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