Phase transitions in Li, K and Ag modified Na1/2Bi 1/2TiO3-SrTiO3-PbTiO3 solid solutions

M. Dunce; E. Birks; M. Antonova; A. Plaude; A. Sternberg

doi:10.1080/10584587.2012.730948

Phase transitions in Li, K and Ag modified Na_1/2Bi _1/2TiO₃-SrTiO₃-PbTiO₃ solid solutions

M. Dunce^*
, E. Birks
, M. Antonova
, A. Plaude
, A. Sternberg

^*Corresponding author for this work

University of Latvia

Research output: Contribution to journal › Conference article › peer-review

Abstract

Influence of moderate substitution of Na by monovalent metals Li, Kand Ag on structure, phase transitions and dielectric properties of 0.4Na _1/2Bi_1/2Ti O₃-0.4SrTiO₃-0. 2PbTiO₃ is studied. Substitution by Li increases, while substitution by K and Ag decreases tetragonality of unit cell. Li increases, Ag decreases while K weakly influences phase transition temperature. The characteristic for the parent phase relaxor state with T_t approaching T_m in case of substitution by Kand Li transfers into diffused phase transition without T_m dependence on frequency and extended region of thermal hysteresis.

Original language	English
Pages (from-to)	12-18
Number of pages	7
Journal	Ferroelectrics
Volume	436
Issue number	1
DOIs	https://doi.org/10.1080/10584587.2012.730948
Publication status	Published - 2012
Event	International Conference on Functional Materials and Nanotechnologies, FM and NT 2012 - Riga, Latvia Duration: 17 Apr 2012 → 20 Apr 2012

Keywords

Modificators
NBT
Phase transitions
Relaxors
Solid solutions

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10.1080/10584587.2012.730948

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title = "Phase transitions in Li, K and Ag modified Na1/2Bi 1/2TiO3-SrTiO3-PbTiO3 solid solutions",

abstract = "Influence of moderate substitution of Na by monovalent metals Li, Kand Ag on structure, phase transitions and dielectric properties of 0.4Na 1/2Bi1/2Ti O3-0.4SrTiO3-0. 2PbTiO3 is studied. Substitution by Li increases, while substitution by K and Ag decreases tetragonality of unit cell. Li increases, Ag decreases while K weakly influences phase transition temperature. The characteristic for the parent phase relaxor state with Tt approaching Tm in case of substitution by Kand Li transfers into diffused phase transition without Tm dependence on frequency and extended region of thermal hysteresis.",

keywords = "Modificators, NBT, Phase transitions, Relaxors, Solid solutions",

author = "M. Dunce and E. Birks and M. Antonova and A. Plaude and A. Sternberg",

year = "2012",

doi = "10.1080/10584587.2012.730948",

language = "English",

volume = "436",

pages = "12--18",

journal = "Ferroelectrics",

issn = "0015-0193",

publisher = "Taylor and Francis Ltd.",

number = "1",

note = "International Conference on Functional Materials and Nanotechnologies, FM and NT 2012 ; Conference date: 17-04-2012 Through 20-04-2012",

}

TY - JOUR

T1 - Phase transitions in Li, K and Ag modified Na1/2Bi 1/2TiO3-SrTiO3-PbTiO3 solid solutions

AU - Dunce, M.

AU - Birks, E.

AU - Antonova, M.

AU - Plaude, A.

AU - Sternberg, A.

PY - 2012

Y1 - 2012

N2 - Influence of moderate substitution of Na by monovalent metals Li, Kand Ag on structure, phase transitions and dielectric properties of 0.4Na 1/2Bi1/2Ti O3-0.4SrTiO3-0. 2PbTiO3 is studied. Substitution by Li increases, while substitution by K and Ag decreases tetragonality of unit cell. Li increases, Ag decreases while K weakly influences phase transition temperature. The characteristic for the parent phase relaxor state with Tt approaching Tm in case of substitution by Kand Li transfers into diffused phase transition without Tm dependence on frequency and extended region of thermal hysteresis.

AB - Influence of moderate substitution of Na by monovalent metals Li, Kand Ag on structure, phase transitions and dielectric properties of 0.4Na 1/2Bi1/2Ti O3-0.4SrTiO3-0. 2PbTiO3 is studied. Substitution by Li increases, while substitution by K and Ag decreases tetragonality of unit cell. Li increases, Ag decreases while K weakly influences phase transition temperature. The characteristic for the parent phase relaxor state with Tt approaching Tm in case of substitution by Kand Li transfers into diffused phase transition without Tm dependence on frequency and extended region of thermal hysteresis.

KW - Modificators

KW - NBT

KW - Phase transitions

KW - Relaxors

KW - Solid solutions

UR - https://www.scopus.com/pages/publications/84875902105

U2 - 10.1080/10584587.2012.730948

DO - 10.1080/10584587.2012.730948

M3 - Conference article

AN - SCOPUS:84875902105

SN - 0015-0193

VL - 436

SP - 12

EP - 18

JO - Ferroelectrics

JF - Ferroelectrics

IS - 1

T2 - International Conference on Functional Materials and Nanotechnologies, FM and NT 2012

Y2 - 17 April 2012 through 20 April 2012

ER -

Phase transitions in Li, K and Ag modified Na_1/2Bi _1/2TiO₃-SrTiO₃-PbTiO₃ solid solutions

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Keywords

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