Abstract
The effect of the modification of the structure of azobenzene molecule by introduction a variety of functional groups on the photoisomerization in Langmuir-Blodgett and vacuum evaporated films has been investigated. The switching effect of the absorption, the surface potential and the electrical properties in thin layers of compounds has been discussed. A novel approach to the design of azobenzene amphiphiles, such as introduction of large bulky substituents in the molecule providing for a free volume necessary for the trans-to-cis photoisomerization, gave a number of valuable photochromic materials for investigation of reversible optically induced switching processes.
| Original language | English |
|---|---|
| Pages (from-to) | 381-400 |
| Number of pages | 20 |
| Journal | Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals |
| Volume | 355 |
| DOIs | |
| Publication status | Published - Jan 2001 |
| Externally published | Yes |
Keywords
- Absorption
- Azobenzene derivatives
- Langmuir-Blodget films
- Optically induced switching
- Surface potential
- Vacuum evaporated films
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