Specific features of absorption and DSC for the DEA-CuCl4 nanoparticles incorporated into the PMMA polymer matrices

K. Ozga; M. Piasecki; S. Tkaczyk; B. Kapustianyk; P. Bragiel; A. H. Reshak; M. G. Brik; I. V. Kityk

doi:10.1016/j.physb.2008.01.027

Specific features of absorption and DSC for the DEA-CuCl₄ nanoparticles incorporated into the PMMA polymer matrices

K. Ozga
, M. Piasecki
, S. Tkaczyk
, B. Kapustianyk
, P. Bragiel
, A. H. Reshak
, M. G. Brik
, I. V. Kityk^*

^*Corresponding author for this work

Częstochowa University of Technology
Jan Dlugosz University in Czestochowa
Ivan Franko National University of L'viv
University of South Bohemia
University of Tartu

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Diethylammonium tetrachlorcuprate NH₂(C₂H₅)₂CuCl₄ (DEA-CuCl₄) nanoparticles with sizes about 10 nm were synthesized and embedded into the PMMA polymer matrices. Using DSC temperature study a substantial influence of the polymer matrix on the phase transition temperatures was shown, reflecting a disturbing effect of principal 3d Cu-3p Cl metal-ligand charge transfer bands. Dependence of the absorption spectra on the nanocrystallites (NC) concentration was studied. It was established that an increase of the NC content results in spectral shift of CuCl₄ absorption bands. Explanation of this phenomenon has been suggested within a framework of first principle crystal field quantum chemical calculations.

Original language	English
Pages (from-to)	2561-2566
Number of pages	6
Journal	Physica B: Condensed Matter
Volume	403
Issue number	17
DOIs	https://doi.org/10.1016/j.physb.2008.01.027
Publication status	Published - 1 Aug 2008
Externally published	Yes

Keywords

Nanocrystallites
Optical materials
Polymer nanocomposites

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10.1016/j.physb.2008.01.027

Cite this

@article{f7dc80da9db041e8812dd47b90114f85,

title = "Specific features of absorption and DSC for the DEA-CuCl4 nanoparticles incorporated into the PMMA polymer matrices",

abstract = "Diethylammonium tetrachlorcuprate NH2(C2H5)2CuCl4 (DEA-CuCl4) nanoparticles with sizes about 10 nm were synthesized and embedded into the PMMA polymer matrices. Using DSC temperature study a substantial influence of the polymer matrix on the phase transition temperatures was shown, reflecting a disturbing effect of principal 3d Cu-3p Cl metal-ligand charge transfer bands. Dependence of the absorption spectra on the nanocrystallites (NC) concentration was studied. It was established that an increase of the NC content results in spectral shift of CuCl4 absorption bands. Explanation of this phenomenon has been suggested within a framework of first principle crystal field quantum chemical calculations.",

keywords = "Nanocrystallites, Optical materials, Polymer nanocomposites",

author = "K. Ozga and M. Piasecki and S. Tkaczyk and B. Kapustianyk and P. Bragiel and Reshak, \{A. H.\} and Brik, \{M. G.\} and Kityk, \{I. V.\}",

year = "2008",

month = aug,

day = "1",

doi = "10.1016/j.physb.2008.01.027",

language = "English",

volume = "403",

pages = "2561--2566",

journal = "Physica B: Condensed Matter",

issn = "0921-4526",

publisher = "Elsevier B.V.",

number = "17",

}

TY - JOUR

T1 - Specific features of absorption and DSC for the DEA-CuCl4 nanoparticles incorporated into the PMMA polymer matrices

AU - Ozga, K.

AU - Piasecki, M.

AU - Tkaczyk, S.

AU - Kapustianyk, B.

AU - Bragiel, P.

AU - Reshak, A. H.

AU - Brik, M. G.

AU - Kityk, I. V.

PY - 2008/8/1

Y1 - 2008/8/1

N2 - Diethylammonium tetrachlorcuprate NH2(C2H5)2CuCl4 (DEA-CuCl4) nanoparticles with sizes about 10 nm were synthesized and embedded into the PMMA polymer matrices. Using DSC temperature study a substantial influence of the polymer matrix on the phase transition temperatures was shown, reflecting a disturbing effect of principal 3d Cu-3p Cl metal-ligand charge transfer bands. Dependence of the absorption spectra on the nanocrystallites (NC) concentration was studied. It was established that an increase of the NC content results in spectral shift of CuCl4 absorption bands. Explanation of this phenomenon has been suggested within a framework of first principle crystal field quantum chemical calculations.

AB - Diethylammonium tetrachlorcuprate NH2(C2H5)2CuCl4 (DEA-CuCl4) nanoparticles with sizes about 10 nm were synthesized and embedded into the PMMA polymer matrices. Using DSC temperature study a substantial influence of the polymer matrix on the phase transition temperatures was shown, reflecting a disturbing effect of principal 3d Cu-3p Cl metal-ligand charge transfer bands. Dependence of the absorption spectra on the nanocrystallites (NC) concentration was studied. It was established that an increase of the NC content results in spectral shift of CuCl4 absorption bands. Explanation of this phenomenon has been suggested within a framework of first principle crystal field quantum chemical calculations.

KW - Nanocrystallites

KW - Optical materials

KW - Polymer nanocomposites

UR - https://www.scopus.com/pages/publications/60049087747

U2 - 10.1016/j.physb.2008.01.027

DO - 10.1016/j.physb.2008.01.027

M3 - Article

AN - SCOPUS:60049087747

SN - 0921-4526

VL - 403

SP - 2561

EP - 2566

JO - Physica B: Condensed Matter

JF - Physica B: Condensed Matter

IS - 17

ER -

Specific features of absorption and DSC for the DEA-CuCl₄ nanoparticles incorporated into the PMMA polymer matrices

Abstract

Keywords

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