Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3

A. M. Srivastava; H. A. Comanzo; D. J. Smith; J. W. Choi; M. G. Brik; W. W. Beers; S. A. Payne

doi:10.1016/j.jlumin.2018.10.090

Spectroscopy of Mn⁴⁺ in orthorhombic perovskite, LaInO₃

A. M. Srivastava^*
, H. A. Comanzo
, D. J. Smith
, J. W. Choi
, M. G. Brik
, W. W. Beers
, S. A. Payne

^*Corresponding author for this work

General Electric
Chongqing University of Posts and Telecommunications
University of Tartu
Jan Dlugosz University in Czestochowa
Lawrence Livermore National Laboratory

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

The low temperature spectroscopic properties of Mn⁴⁺ (3d³) in the orthorhombic perovskite, LaInO₃, is examined in this work. The exchange charge model of crystal-field theory is used to calculate the Mn⁴⁺ energy levels. The spectra can be fitted by the parameters Dq = 1776 cm⁻¹, B = 700 cm⁻¹ and C = 3189 cm⁻¹, with C/B = 4.5. Discussions pertaining to the low luminescence efficiency of LaInO₃:Mn⁴⁺ are presented. A comparative study of the variations in the energy of the ²E_g→⁴A_2g emission transition in a series of materials with the perovskite structure is presented. The data suggest a relationship between the energy of the ²E_g→⁴A_2g emission transition and the deviation of the octahedral O-Mn-O bond angle from the ideal 90°. It is concluded that the angular distortion is not large enough to support the development of high luminosity Mn⁴⁺ activated phosphors in the ABO₃ perovskite family of materials.

Original language	English
Pages (from-to)	398-402
Number of pages	5
Journal	Journal of Luminescence
Volume	206
DOIs	https://doi.org/10.1016/j.jlumin.2018.10.090
Publication status	Published - Feb 2019
Externally published	Yes

Keywords

Crystal-field theory
LaInO
Luminescence
Mn
MnO distortion
Perovskite

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10.1016/j.jlumin.2018.10.090

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@article{3458a3d3e2834c1baed90d2d482e9fb9,

title = "Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3 ",

abstract = "The low temperature spectroscopic properties of Mn4+ (3d3) in the orthorhombic perovskite, LaInO3, is examined in this work. The exchange charge model of crystal-field theory is used to calculate the Mn4+ energy levels. The spectra can be fitted by the parameters Dq = 1776 cm−1, B = 700 cm−1 and C = 3189 cm−1, with C/B = 4.5. Discussions pertaining to the low luminescence efficiency of LaInO3:Mn4+ are presented. A comparative study of the variations in the energy of the 2Eg→4A2g emission transition in a series of materials with the perovskite structure is presented. The data suggest a relationship between the energy of the 2Eg→4A2g emission transition and the deviation of the octahedral O-Mn-O bond angle from the ideal 90°. It is concluded that the angular distortion is not large enough to support the development of high luminosity Mn4+ activated phosphors in the ABO3 perovskite family of materials.",

keywords = "Crystal-field theory, LaInO, Luminescence, Mn, MnO distortion, Perovskite",

author = "Srivastava, \{A. M.\} and Comanzo, \{H. A.\} and Smith, \{D. J.\} and Choi, \{J. W.\} and Brik, \{M. G.\} and Beers, \{W. W.\} and Payne, \{S. A.\}",

note = "Publisher Copyright: {\textcopyright} 2018",

year = "2019",

month = feb,

doi = "10.1016/j.jlumin.2018.10.090",

language = "English",

volume = "206",

pages = "398--402",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Spectroscopy of Mn4+ in orthorhombic perovskite, LaInO3

AU - Srivastava, A. M.

AU - Comanzo, H. A.

AU - Smith, D. J.

AU - Choi, J. W.

AU - Brik, M. G.

AU - Beers, W. W.

AU - Payne, S. A.

PY - 2019/2

Y1 - 2019/2

N2 - The low temperature spectroscopic properties of Mn4+ (3d3) in the orthorhombic perovskite, LaInO3, is examined in this work. The exchange charge model of crystal-field theory is used to calculate the Mn4+ energy levels. The spectra can be fitted by the parameters Dq = 1776 cm−1, B = 700 cm−1 and C = 3189 cm−1, with C/B = 4.5. Discussions pertaining to the low luminescence efficiency of LaInO3:Mn4+ are presented. A comparative study of the variations in the energy of the 2Eg→4A2g emission transition in a series of materials with the perovskite structure is presented. The data suggest a relationship between the energy of the 2Eg→4A2g emission transition and the deviation of the octahedral O-Mn-O bond angle from the ideal 90°. It is concluded that the angular distortion is not large enough to support the development of high luminosity Mn4+ activated phosphors in the ABO3 perovskite family of materials.

AB - The low temperature spectroscopic properties of Mn4+ (3d3) in the orthorhombic perovskite, LaInO3, is examined in this work. The exchange charge model of crystal-field theory is used to calculate the Mn4+ energy levels. The spectra can be fitted by the parameters Dq = 1776 cm−1, B = 700 cm−1 and C = 3189 cm−1, with C/B = 4.5. Discussions pertaining to the low luminescence efficiency of LaInO3:Mn4+ are presented. A comparative study of the variations in the energy of the 2Eg→4A2g emission transition in a series of materials with the perovskite structure is presented. The data suggest a relationship between the energy of the 2Eg→4A2g emission transition and the deviation of the octahedral O-Mn-O bond angle from the ideal 90°. It is concluded that the angular distortion is not large enough to support the development of high luminosity Mn4+ activated phosphors in the ABO3 perovskite family of materials.

KW - Crystal-field theory

KW - LaInO

KW - Luminescence

KW - Mn

KW - MnO distortion

KW - Perovskite

UR - https://www.scopus.com/pages/publications/85055693583

U2 - 10.1016/j.jlumin.2018.10.090

DO - 10.1016/j.jlumin.2018.10.090

M3 - Article

AN - SCOPUS:85055693583

SN - 0022-2313

VL - 206

SP - 398

EP - 402

JO - Journal of Luminescence

JF - Journal of Luminescence

ER -

Spectroscopy of Mn⁴⁺ in orthorhombic perovskite, LaInO₃

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Keywords

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