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Synthesis and nonlinear optical properties of novel N,N-dihydroxyethyl based molecular organic glasses using triaryl substitutes as amorphous phase formation enhancers

  • Riga Technical University

Research output: Chapter in Book/Report/Conference proceedingConference paperResearchpeer-review

1 Citation (Scopus)

Abstract

In given study a new structural design of molecular NLO materials is presented where amorphous phase formation is achieved by introduction of bulky trityl and triphenylsilyl substituents. Obtained materials formed stable organic glasses with good optical quality and glass transition temperatures notably exceeding ambient. NLO activity was successfully measured in samples that underwent corona discharge poling. The comparison of both enhancer groups revealed, that trityl group increases thermal sustainability of material, while triphenylsilyl group better promotes formation and stability of amorphous phase.

Original languageEnglish
Title of host publicationLinear and Nonlinear Optics of Organic Materials XI
DOIs
Publication statusPublished - 2011
EventLinear and Nonlinear Optics of Organic Materials XI - San Diego, CA, United States
Duration: 21 Aug 201122 Aug 2011

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume8113
ISSN (Print)0277-786X

Conference

ConferenceLinear and Nonlinear Optics of Organic Materials XI
Country/TerritoryUnited States
CitySan Diego, CA
Period21/08/1122/08/11

Keywords

  • Azobenzene
  • Molecular glasses
  • NLO efficiency
  • Second harmonic generation

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