Synthesis and x-ray structural investigation of bismuth 2-methyl-8-quinolineselenolate Bi[C9H5(CH 3)NSe]3

E. Silina; S. Belyakov; J. Ashaks; A. Tokmakov; L. Pech; D. Zaruma

doi:10.1007/s10593-009-0347-y

Synthesis and x-ray structural investigation of bismuth 2-methyl-8-quinolineselenolate Bi[C₉H₅(CH ₃)NSe]₃

E. Silina
, S. Belyakov^*
, J. Ashaks
, A. Tokmakov
, L. Pech
, D. Zaruma

^*Corresponding author for this work

Riga Technical University
Latvian Institute of Organic Synthesis

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Bismuth 2-methyl-8-quinolineselenolate, Bi[C₉H ₅(CH₃)NSe]₃, was synthesized. X-ray analysis was used to determine the structure of this complex. The crystal chemistry of bismuth(III), antimony(III), and arsenic(III) 2-methyl-8-quinolineselenolates and 2-methyl-8-quinolinethiolates was discussed relative to the effect of going from Se to S as the ligand atoms and presence of a methyl group at C-2 of the quinoline system and unshared electron pair of the central atom in the complex.

Original language	English
Pages (from-to)	860-865
Number of pages	6
Journal	Chemistry of Heterocyclic Compounds
Volume	45
Issue number	7
DOIs	https://doi.org/10.1007/s10593-009-0347-y
Publication status	Published - Jul 2009
Externally published	Yes

Keywords

And arsenic(III) 2-methyl-8-quinolineselenolates and 2-methyl-8-quinolinethiolates
Antimony(III)
Bismuth(III)
Unshared electron pair
X-ray structural analysis

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10.1007/s10593-009-0347-y

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title = "Synthesis and x-ray structural investigation of bismuth 2-methyl-8-quinolineselenolate Bi[C9H5(CH 3)NSe]3",

abstract = "Bismuth 2-methyl-8-quinolineselenolate, Bi[C9H 5(CH3)NSe]3, was synthesized. X-ray analysis was used to determine the structure of this complex. The crystal chemistry of bismuth(III), antimony(III), and arsenic(III) 2-methyl-8-quinolineselenolates and 2-methyl-8-quinolinethiolates was discussed relative to the effect of going from Se to S as the ligand atoms and presence of a methyl group at C-2 of the quinoline system and unshared electron pair of the central atom in the complex.",

keywords = "And arsenic(III) 2-methyl-8-quinolineselenolates and 2-methyl-8-quinolinethiolates, Antimony(III), Bismuth(III), Unshared electron pair, X-ray structural analysis",

author = "E. Silina and S. Belyakov and J. Ashaks and A. Tokmakov and L. Pech and D. Zaruma",

year = "2009",

month = jul,

doi = "10.1007/s10593-009-0347-y",

language = "English",

volume = "45",

pages = "860--865",

journal = "Chemistry of Heterocyclic Compounds",

issn = "0009-3122",

publisher = "Springer",

number = "7",

}

TY - JOUR

T1 - Synthesis and x-ray structural investigation of bismuth 2-methyl-8-quinolineselenolate Bi[C9H5(CH 3)NSe]3

AU - Silina, E.

AU - Belyakov, S.

AU - Ashaks, J.

AU - Tokmakov, A.

AU - Pech, L.

AU - Zaruma, D.

PY - 2009/7

Y1 - 2009/7

N2 - Bismuth 2-methyl-8-quinolineselenolate, Bi[C9H 5(CH3)NSe]3, was synthesized. X-ray analysis was used to determine the structure of this complex. The crystal chemistry of bismuth(III), antimony(III), and arsenic(III) 2-methyl-8-quinolineselenolates and 2-methyl-8-quinolinethiolates was discussed relative to the effect of going from Se to S as the ligand atoms and presence of a methyl group at C-2 of the quinoline system and unshared electron pair of the central atom in the complex.

AB - Bismuth 2-methyl-8-quinolineselenolate, Bi[C9H 5(CH3)NSe]3, was synthesized. X-ray analysis was used to determine the structure of this complex. The crystal chemistry of bismuth(III), antimony(III), and arsenic(III) 2-methyl-8-quinolineselenolates and 2-methyl-8-quinolinethiolates was discussed relative to the effect of going from Se to S as the ligand atoms and presence of a methyl group at C-2 of the quinoline system and unshared electron pair of the central atom in the complex.

KW - And arsenic(III) 2-methyl-8-quinolineselenolates and 2-methyl-8-quinolinethiolates

KW - Antimony(III)

KW - Bismuth(III)

KW - Unshared electron pair

KW - X-ray structural analysis

UR - https://www.scopus.com/pages/publications/70450267572

U2 - 10.1007/s10593-009-0347-y

DO - 10.1007/s10593-009-0347-y

M3 - Article

AN - SCOPUS:70450267572

SN - 0009-3122

VL - 45

SP - 860

EP - 865

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

IS - 7

ER -

Synthesis and x-ray structural investigation of bismuth 2-methyl-8-quinolineselenolate Bi[C₉H₅(CH ₃)NSe]₃

Abstract

Keywords

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