Theoretical analysis of optical spectra of Ce3+ in multi-sites host compounds

M. G. Brik; C. G. Ma; Hongbin Liang; Haiyong Ni; Guokui Liu

doi:10.1016/j.jlumin.2013.09.073

Theoretical analysis of optical spectra of Ce³⁺ in multi-sites host compounds

M. G. Brik^*
, C. G. Ma
, Hongbin Liang
, Haiyong Ni
, Guokui Liu

^*Corresponding author for this work

University of Tartu
Chongqing University of Posts and Telecommunications
Sun Yat-Sen University
Argonne National Laboratory

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Theoretical analysis of optical properties of two recently synthesized phosphors with the Ce³⁺ ions (Na₃LuSi₂O ₇ and NaSr₄(BO₃)₃) was performed. The exchange charge model of crystal field was used to calculate the crystal field parameters and cerium 5d states splittings for each site in Na ₃LuSi₂O₇. Analysis of vibronic coupling of Ce³⁺ in NaSr₄(BO₃)₃ resulted in a quantitative modeling and theoretical simulation of the experimental spectra. Electronic energy levels, vibrational frequencies and ion-lattice vibronic coupling strength are determined specifically for Ce³⁺ at different sites. The performed analysis allows for getting detailed description of the optical properties of trivalent cerium in the considered crystals and provides a general guide to understanding and characterizing other Ce³⁺ activated phosphors.

Original language	English
Pages (from-to)	203-205
Number of pages	3
Journal	Journal of Luminescence
Volume	152
DOIs	https://doi.org/10.1016/j.jlumin.2013.09.073
Publication status	Published - Aug 2014
Externally published	Yes

Keywords

5d-4f emission
Crystal field splitting
Electron-vibrational coupling

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10.1016/j.jlumin.2013.09.073

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title = "Theoretical analysis of optical spectra of Ce3+ in multi-sites host compounds",

abstract = "Theoretical analysis of optical properties of two recently synthesized phosphors with the Ce3+ ions (Na3LuSi2O 7 and NaSr4(BO3)3) was performed. The exchange charge model of crystal field was used to calculate the crystal field parameters and cerium 5d states splittings for each site in Na 3LuSi2O7. Analysis of vibronic coupling of Ce3+ in NaSr4(BO3)3 resulted in a quantitative modeling and theoretical simulation of the experimental spectra. Electronic energy levels, vibrational frequencies and ion-lattice vibronic coupling strength are determined specifically for Ce3+ at different sites. The performed analysis allows for getting detailed description of the optical properties of trivalent cerium in the considered crystals and provides a general guide to understanding and characterizing other Ce3+ activated phosphors.",

keywords = "5d-4f emission, Crystal field splitting, Electron-vibrational coupling",

author = "Brik, \{M. G.\} and Ma, \{C. G.\} and Hongbin Liang and Haiyong Ni and Guokui Liu",

year = "2014",

month = aug,

doi = "10.1016/j.jlumin.2013.09.073",

language = "English",

volume = "152",

pages = "203--205",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Theoretical analysis of optical spectra of Ce3+ in multi-sites host compounds

AU - Brik, M. G.

AU - Ma, C. G.

AU - Liang, Hongbin

AU - Ni, Haiyong

AU - Liu, Guokui

PY - 2014/8

Y1 - 2014/8

N2 - Theoretical analysis of optical properties of two recently synthesized phosphors with the Ce3+ ions (Na3LuSi2O 7 and NaSr4(BO3)3) was performed. The exchange charge model of crystal field was used to calculate the crystal field parameters and cerium 5d states splittings for each site in Na 3LuSi2O7. Analysis of vibronic coupling of Ce3+ in NaSr4(BO3)3 resulted in a quantitative modeling and theoretical simulation of the experimental spectra. Electronic energy levels, vibrational frequencies and ion-lattice vibronic coupling strength are determined specifically for Ce3+ at different sites. The performed analysis allows for getting detailed description of the optical properties of trivalent cerium in the considered crystals and provides a general guide to understanding and characterizing other Ce3+ activated phosphors.

AB - Theoretical analysis of optical properties of two recently synthesized phosphors with the Ce3+ ions (Na3LuSi2O 7 and NaSr4(BO3)3) was performed. The exchange charge model of crystal field was used to calculate the crystal field parameters and cerium 5d states splittings for each site in Na 3LuSi2O7. Analysis of vibronic coupling of Ce3+ in NaSr4(BO3)3 resulted in a quantitative modeling and theoretical simulation of the experimental spectra. Electronic energy levels, vibrational frequencies and ion-lattice vibronic coupling strength are determined specifically for Ce3+ at different sites. The performed analysis allows for getting detailed description of the optical properties of trivalent cerium in the considered crystals and provides a general guide to understanding and characterizing other Ce3+ activated phosphors.

KW - 5d-4f emission

KW - Crystal field splitting

KW - Electron-vibrational coupling

UR - https://www.scopus.com/pages/publications/84899632666

U2 - 10.1016/j.jlumin.2013.09.073

DO - 10.1016/j.jlumin.2013.09.073

M3 - Article

AN - SCOPUS:84899632666

SN - 0022-2313

VL - 152

SP - 203

EP - 205

JO - Journal of Luminescence

JF - Journal of Luminescence

ER -

Theoretical analysis of optical spectra of Ce³⁺ in multi-sites host compounds

Abstract

Keywords

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