Characterization of Na1.3Al0.3Zr1.7(PO4)3 solid electrolyte ceramics by impedance spectroscopy

E. Kazakevičius; A. Kežionis; L. Žukauskaite; M. Barré; T. Šalkus; A. Žalga; A. Selskis; A. Orliukas

doi:10.1016/j.ssi.2014.09.038

Characterization of Na_1.3Al_0.3Zr_1.7(PO₄)₃ solid electrolyte ceramics by impedance spectroscopy

E. Kazakevičius^*
, A. Kežionis
, L. Žukauskaite
, M. Barré
, T. Šalkus
, A. Žalga
, A. Selskis
, A. Orliukas

^*Šī darba korespondējošais autors

Vilnius University
Institut des Molécules et Matériaux du Mans
Center for Physical Sciences and Technology

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

7 Atsauces (Scopus)

Kopsavilkums

The NASICON-type Na_1.3Al_0.3Zr_1.7(PO₄)₃ compound has been synthesized by Pechini method. The investigation of the electrical properties was performed in 10 Hz-3 · 10⁹ Hz and 300-500 K frequency and temperature ranges by means of impedance spectroscopy. The results allowed us to explore the properties of dispersion of electrical properties attributed to charge carrier relaxation. The distribution of relaxation times function was obtained for experimental data by numerically solving a set of integral equations. To reveal the influence of compositional variations on electrical properties the results were compared with the ones of Na_1.3Al_0.3Ti_1.7(PO₄)₃.

Oriģinālvaloda	Angļu
Lapas (no-līdz)	128-133
Lapu skaits	6
Žurnāls	Solid State Ionics
Sējums	271
DOIs	https://doi.org/10.1016/j.ssi.2014.09.038
Publikācijas statuss	Publicēts - marts 2015
Ārēji publicēts	Jā

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title = "Characterization of Na1.3Al0.3Zr1.7(PO4)3 solid electrolyte ceramics by impedance spectroscopy",

abstract = "The NASICON-type Na1.3Al0.3Zr1.7(PO4)3 compound has been synthesized by Pechini method. The investigation of the electrical properties was performed in 10 Hz-3 · 109 Hz and 300-500 K frequency and temperature ranges by means of impedance spectroscopy. The results allowed us to explore the properties of dispersion of electrical properties attributed to charge carrier relaxation. The distribution of relaxation times function was obtained for experimental data by numerically solving a set of integral equations. To reveal the influence of compositional variations on electrical properties the results were compared with the ones of Na1.3Al0.3Ti1.7(PO4)3.",

keywords = "Electrolyte, Impedance, NASICON",

author = "E. Kazakevi{\v c}ius and A. Ke{\v z}ionis and L. {\v Z}ukauskaite and M. Barr{\'e} and T. {\v S}alkus and A. {\v Z}alga and A. Selskis and A. Orliukas",

year = "2015",

month = mar,

doi = "10.1016/j.ssi.2014.09.038",

language = "English",

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journal = "Solid State Ionics",

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TY - JOUR

T1 - Characterization of Na1.3Al0.3Zr1.7(PO4)3 solid electrolyte ceramics by impedance spectroscopy

AU - Kazakevičius, E.

AU - Kežionis, A.

AU - Žukauskaite, L.

AU - Barré, M.

AU - Šalkus, T.

AU - Žalga, A.

AU - Selskis, A.

AU - Orliukas, A.

PY - 2015/3

Y1 - 2015/3

N2 - The NASICON-type Na1.3Al0.3Zr1.7(PO4)3 compound has been synthesized by Pechini method. The investigation of the electrical properties was performed in 10 Hz-3 · 109 Hz and 300-500 K frequency and temperature ranges by means of impedance spectroscopy. The results allowed us to explore the properties of dispersion of electrical properties attributed to charge carrier relaxation. The distribution of relaxation times function was obtained for experimental data by numerically solving a set of integral equations. To reveal the influence of compositional variations on electrical properties the results were compared with the ones of Na1.3Al0.3Ti1.7(PO4)3.

AB - The NASICON-type Na1.3Al0.3Zr1.7(PO4)3 compound has been synthesized by Pechini method. The investigation of the electrical properties was performed in 10 Hz-3 · 109 Hz and 300-500 K frequency and temperature ranges by means of impedance spectroscopy. The results allowed us to explore the properties of dispersion of electrical properties attributed to charge carrier relaxation. The distribution of relaxation times function was obtained for experimental data by numerically solving a set of integral equations. To reveal the influence of compositional variations on electrical properties the results were compared with the ones of Na1.3Al0.3Ti1.7(PO4)3.

KW - Electrolyte

KW - Impedance

KW - NASICON

UR - https://www.scopus.com/pages/publications/85027954628

U2 - 10.1016/j.ssi.2014.09.038

DO - 10.1016/j.ssi.2014.09.038

M3 - Article

AN - SCOPUS:85027954628

SN - 0167-2738

VL - 271

SP - 128

EP - 133

JO - Solid State Ionics

JF - Solid State Ionics

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