Copper-Catalyzed para-Selective C-H Amination of Electron-Rich Arenes

Beatrise Berzina; Igors Sokolovs; Edgars Suna

doi:10.1021/acscatal.5b01992

Copper-Catalyzed para-Selective C-H Amination of Electron-Rich Arenes

Beatrise Berzina
, Igors Sokolovs
, Edgars Suna^*

^*Šī darba korespondējošais autors

Latvian Institute of Organic Synthesis

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

68 Atsauces (Scopus)

Kopsavilkums

A one-pot two-step method for para-selective C-H amination of carbocyclic arenes comprises the in situ formation of unsymmetrical diaryl-λ³-iodanes followed by their Cu(I)-catalyzed reaction with a range of N-unprotected amines.

Oriģinālvaloda	Angļu
Lapas (no-līdz)	7008-7014
Lapu skaits	7
Žurnāls	ACS Catalysis
Sējums	5
Izdevuma numurs	11
DOIs	https://doi.org/10.1021/acscatal.5b01992 https://doi.org/10.1021/acscatal.5b01992
Publikācijas statuss	Publicēts - 6 nov. 2015
Ārēji publicēts	Jā

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title = "Copper-Catalyzed para-Selective C-H Amination of Electron-Rich Arenes",

abstract = "A one-pot two-step method for para-selective C-H amination of carbocyclic arenes comprises the in situ formation of unsymmetrical diaryl-λ3-iodanes followed by their Cu(I)-catalyzed reaction with a range of N-unprotected amines.",

keywords = "amination, copper, diaryliodonium salts, hypervalent iodine, regioselectivity",

author = "Beatrise Berzina and Igors Sokolovs and Edgars Suna",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = nov,

day = "6",

doi = "10.1021/acscatal.5b01992",

language = "English",

volume = "5",

pages = "7008--7014",

journal = "ACS Catalysis",

issn = "2155-5435",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Copper-Catalyzed para-Selective C-H Amination of Electron-Rich Arenes

AU - Berzina, Beatrise

AU - Sokolovs, Igors

AU - Suna, Edgars

PY - 2015/11/6

Y1 - 2015/11/6

N2 - A one-pot two-step method for para-selective C-H amination of carbocyclic arenes comprises the in situ formation of unsymmetrical diaryl-λ3-iodanes followed by their Cu(I)-catalyzed reaction with a range of N-unprotected amines.

AB - A one-pot two-step method for para-selective C-H amination of carbocyclic arenes comprises the in situ formation of unsymmetrical diaryl-λ3-iodanes followed by their Cu(I)-catalyzed reaction with a range of N-unprotected amines.

KW - amination

KW - copper

KW - diaryliodonium salts

KW - hypervalent iodine

KW - regioselectivity

UR - https://www.scopus.com/pages/publications/84946823984

U2 - 10.1021/acscatal.5b01992

DO - 10.1021/acscatal.5b01992

M3 - Article

AN - SCOPUS:84946823984

SN - 2155-5435

VL - 5

SP - 7008

EP - 7014

JO - ACS Catalysis

JF - ACS Catalysis

IS - 11

ER -

Copper-Catalyzed para-Selective C-H Amination of Electron-Rich Arenes

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