Doping strategies for increased performance in BiFeO3

V. A. Khomchenko; D. A. Kiselev; M. Kopcewicz; M. Maglione; V. V. Shvartsman; P. Borisov; W. Kleemann; A. M.L. Lopes; Y. G. Pogorelov; J. P. Araujo; R. M. Rubinger; N. A. Sobolev; J. M. Vieira; A. L. Kholkin

doi:10.1016/j.jmmm.2009.02.008

Doping strategies for increased performance in BiFeO₃

V. A. Khomchenko^*
, D. A. Kiselev
, M. Kopcewicz
, M. Maglione
, V. V. Shvartsman
, P. Borisov
, W. Kleemann
, A. M.L. Lopes
, Y. G. Pogorelov
, J. P. Araujo
, R. M. Rubinger
, N. A. Sobolev
, J. M. Vieira
, A. L. Kholkin

^*Šī darba korespondējošais autors

University of Aveiro
Institute of Microelectronics and Photonics
CNRS
University of Duisburg-Essen
University of Porto

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

178 Atsauces (Scopus)

Kopsavilkums

Investigation of crystal structure, dielectric, magnetic and local ferroelectric properties of the diamagnetically substituted Bi_1-xA_xFeO_3-x/2 (A=Ca, Sr, Pb, Ba; x=0.2, 0.3) polycrystalline samples has been carried out. It has been shown that the heterovalent A²⁺ substitution result in the formation of oxygen vacancies in the host lattice. The solid solutions have been found to possess a rhombohedrally distorted perovskite structure described by the space group R3c. Piezoresponse force microscopy has revealed signs of existence of the ferroelectric polarization in the samples at room temperature. Magnetization measurements have shown that the magnetic state of these compounds is determined by the ionic radius of the substituting elements. A-site substitution with the biggest ionic radius ions has been found to suppress the spiral spin structure of BiFeO₃ giving rise to the appearance of room-temperature weak ferromagnetism.

Oriģinālvaloda	Angļu
Lapas (no-līdz)	1692-1698
Lapu skaits	7
Žurnāls	Journal of Magnetism and Magnetic Materials
Sējums	321
Izdevuma numurs	11
DOIs	https://doi.org/10.1016/j.jmmm.2009.02.008
Publikācijas statuss	Publicēts - jūn. 2009
Ārēji publicēts	Jā

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Khomchenko, V. A., Kiselev, D. A., Kopcewicz, M., Maglione, M., Shvartsman, V. V., Borisov, P., Kleemann, W., Lopes, A. M. L., Pogorelov, Y. G., Araujo, J. P., Rubinger, R. M., Sobolev, N. A., Vieira, J. M., & Kholkin, A. L. (2009). Doping strategies for increased performance in BiFeO₃ Journal of Magnetism and Magnetic Materials, 321(11), 1692-1698. https://doi.org/10.1016/j.jmmm.2009.02.008

@article{12805c2e35ed4d50b9d162a20c9afa31,

title = "Doping strategies for increased performance in BiFeO3 ",

abstract = "Investigation of crystal structure, dielectric, magnetic and local ferroelectric properties of the diamagnetically substituted Bi1-xAxFeO3-x/2 (A=Ca, Sr, Pb, Ba; x=0.2, 0.3) polycrystalline samples has been carried out. It has been shown that the heterovalent A2+ substitution result in the formation of oxygen vacancies in the host lattice. The solid solutions have been found to possess a rhombohedrally distorted perovskite structure described by the space group R3c. Piezoresponse force microscopy has revealed signs of existence of the ferroelectric polarization in the samples at room temperature. Magnetization measurements have shown that the magnetic state of these compounds is determined by the ionic radius of the substituting elements. A-site substitution with the biggest ionic radius ions has been found to suppress the spiral spin structure of BiFeO3 giving rise to the appearance of room-temperature weak ferromagnetism.",

keywords = "BiFeO, Ferroelectricity, Magnetism, Multiferroics",

author = "Khomchenko, \{V. A.\} and Kiselev, \{D. A.\} and M. Kopcewicz and M. Maglione and Shvartsman, \{V. V.\} and P. Borisov and W. Kleemann and Lopes, \{A. M.L.\} and Pogorelov, \{Y. G.\} and Araujo, \{J. P.\} and Rubinger, \{R. M.\} and Sobolev, \{N. A.\} and Vieira, \{J. M.\} and Kholkin, \{A. L.\}",

year = "2009",

month = jun,

doi = "10.1016/j.jmmm.2009.02.008",

language = "English",

volume = "321",

pages = "1692--1698",

journal = "Journal of Magnetism and Magnetic Materials",

issn = "0304-8853",

publisher = "Elsevier B.V.",

number = "11",

}

Khomchenko, VA, Kiselev, DA, Kopcewicz, M, Maglione, M, Shvartsman, VV, Borisov, P, Kleemann, W, Lopes, AML, Pogorelov, YG, Araujo, JP, Rubinger, RM, Sobolev, NA, Vieira, JM & Kholkin, AL 2009, 'Doping strategies for increased performance in BiFeO₃ ', Journal of Magnetism and Magnetic Materials, sēj. 321, Nr. 11, lpp. 1692-1698. https://doi.org/10.1016/j.jmmm.2009.02.008

TY - JOUR

T1 - Doping strategies for increased performance in BiFeO3

AU - Khomchenko, V. A.

AU - Kiselev, D. A.

AU - Kopcewicz, M.

AU - Maglione, M.

AU - Shvartsman, V. V.

AU - Borisov, P.

AU - Kleemann, W.

AU - Lopes, A. M.L.

AU - Pogorelov, Y. G.

AU - Araujo, J. P.

AU - Rubinger, R. M.

AU - Sobolev, N. A.

AU - Vieira, J. M.

AU - Kholkin, A. L.

PY - 2009/6

Y1 - 2009/6

N2 - Investigation of crystal structure, dielectric, magnetic and local ferroelectric properties of the diamagnetically substituted Bi1-xAxFeO3-x/2 (A=Ca, Sr, Pb, Ba; x=0.2, 0.3) polycrystalline samples has been carried out. It has been shown that the heterovalent A2+ substitution result in the formation of oxygen vacancies in the host lattice. The solid solutions have been found to possess a rhombohedrally distorted perovskite structure described by the space group R3c. Piezoresponse force microscopy has revealed signs of existence of the ferroelectric polarization in the samples at room temperature. Magnetization measurements have shown that the magnetic state of these compounds is determined by the ionic radius of the substituting elements. A-site substitution with the biggest ionic radius ions has been found to suppress the spiral spin structure of BiFeO3 giving rise to the appearance of room-temperature weak ferromagnetism.

AB - Investigation of crystal structure, dielectric, magnetic and local ferroelectric properties of the diamagnetically substituted Bi1-xAxFeO3-x/2 (A=Ca, Sr, Pb, Ba; x=0.2, 0.3) polycrystalline samples has been carried out. It has been shown that the heterovalent A2+ substitution result in the formation of oxygen vacancies in the host lattice. The solid solutions have been found to possess a rhombohedrally distorted perovskite structure described by the space group R3c. Piezoresponse force microscopy has revealed signs of existence of the ferroelectric polarization in the samples at room temperature. Magnetization measurements have shown that the magnetic state of these compounds is determined by the ionic radius of the substituting elements. A-site substitution with the biggest ionic radius ions has been found to suppress the spiral spin structure of BiFeO3 giving rise to the appearance of room-temperature weak ferromagnetism.

KW - BiFeO

KW - Ferroelectricity

KW - Magnetism

KW - Multiferroics

UR - https://www.scopus.com/pages/publications/64149105762

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AN - SCOPUS:64149105762

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VL - 321

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JO - Journal of Magnetism and Magnetic Materials

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