Highly functional polyol synthesis from epoxidized tall oil fatty acids

Edgars Vanags; Mikelis Kirpluks; Ugis Cabulis; Zuzana Walterova

doi:10.7569/JRM.2018.634111

Highly functional polyol synthesis from epoxidized tall oil fatty acids

Edgars Vanags^*
, Mikelis Kirpluks
, Ugis Cabulis
, Zuzana Walterova

^*Šī darba korespondējošais autors

Latvian State Institute of Wood Chemistry

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

40 Atsauces (Scopus)

Kopsavilkums

In this work, free tall oil fatty acids were epoxidized with in-situ generated peroxyacetic acid. Reaction kinetics of epoxidation was investigated by oxirane content and iodine value titrimetric determination, as well as FTIR spectra analysis. A highly functional biobased polyol was synthesized by functionalizing epoxidized tall oil fatty acids with triethanolamine using Montmorillonite K10 as a catalyst. The obtained polyol was analyzed by FTIR and MALDI-TOF MS. The most common chemical and physical characteristics of obtained polyol were determined.

Oriģinālvaloda	Angļu
Lapas (no-līdz)	764-771
Lapu skaits	8
Žurnāls	Journal of Renewable Materials
Sējums	6
Izdevuma numurs	7
DOIs	https://doi.org/10.7569/JRM.2018.634111
Publikācijas statuss	Publicēts - dec. 2018
Ārēji publicēts	Jā

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10.7569/JRM.2018.634111

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@article{b8081af7a0ce4a058d9932fa753c402d,

title = "Highly functional polyol synthesis from epoxidized tall oil fatty acids",

abstract = "In this work, free tall oil fatty acids were epoxidized with in-situ generated peroxyacetic acid. Reaction kinetics of epoxidation was investigated by oxirane content and iodine value titrimetric determination, as well as FTIR spectra analysis. A highly functional biobased polyol was synthesized by functionalizing epoxidized tall oil fatty acids with triethanolamine using Montmorillonite K10 as a catalyst. The obtained polyol was analyzed by FTIR and MALDI-TOF MS. The most common chemical and physical characteristics of obtained polyol were determined.",

keywords = "Biobased polyol, Epoxidation, Ion-exchange resin catalyst, Montmorillonite K10, Tall oil fatty acids",

author = "Edgars Vanags and Mikelis Kirpluks and Ugis Cabulis and Zuzana Walterova",

note = "Publisher Copyright: {\textcopyright} 2018 Tech Science Press.",

year = "2018",

month = dec,

doi = "10.7569/JRM.2018.634111",

language = "English",

volume = "6",

pages = "764--771",

journal = "Journal of Renewable Materials",

issn = "2164-6325",

publisher = "Tech Science Press",

number = "7",

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TY - JOUR

T1 - Highly functional polyol synthesis from epoxidized tall oil fatty acids

AU - Vanags, Edgars

AU - Kirpluks, Mikelis

AU - Cabulis, Ugis

AU - Walterova, Zuzana

PY - 2018/12

Y1 - 2018/12

N2 - In this work, free tall oil fatty acids were epoxidized with in-situ generated peroxyacetic acid. Reaction kinetics of epoxidation was investigated by oxirane content and iodine value titrimetric determination, as well as FTIR spectra analysis. A highly functional biobased polyol was synthesized by functionalizing epoxidized tall oil fatty acids with triethanolamine using Montmorillonite K10 as a catalyst. The obtained polyol was analyzed by FTIR and MALDI-TOF MS. The most common chemical and physical characteristics of obtained polyol were determined.

AB - In this work, free tall oil fatty acids were epoxidized with in-situ generated peroxyacetic acid. Reaction kinetics of epoxidation was investigated by oxirane content and iodine value titrimetric determination, as well as FTIR spectra analysis. A highly functional biobased polyol was synthesized by functionalizing epoxidized tall oil fatty acids with triethanolamine using Montmorillonite K10 as a catalyst. The obtained polyol was analyzed by FTIR and MALDI-TOF MS. The most common chemical and physical characteristics of obtained polyol were determined.

KW - Biobased polyol

KW - Epoxidation

KW - Ion-exchange resin catalyst

KW - Montmorillonite K10

KW - Tall oil fatty acids

UR - https://www.scopus.com/pages/publications/85063602277

U2 - 10.7569/JRM.2018.634111

DO - 10.7569/JRM.2018.634111

M3 - Article

AN - SCOPUS:85063602277

SN - 2164-6325

VL - 6

SP - 764

EP - 771

JO - Journal of Renewable Materials

JF - Journal of Renewable Materials

IS - 7

ER -

Highly functional polyol synthesis from epoxidized tall oil fatty acids

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