Interference blockage of electron tunneling and pseudo-Faraday hypercapacity for C-SiO 2 nanocomposites

I. I. Grygorchak; B. A. Lukiyanets; A. Yu Pidluzhna; D. V. Matulka; I. F. Myronyuk

doi:10.1134/S0036024412010116

Interference blockage of electron tunneling and pseudo-Faraday hypercapacity for C-SiO ₂ nanocomposites

I. I. Grygorchak^*
, B. A. Lukiyanets
, A. Yu Pidluzhna
, D. V. Matulka
, I. F. Myronyuk

^*Šī darba korespondējošais autors

Lviv Polytechnic National University
Vasyl Stefanyk Precarpathian National University

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

2 Atsauces (Scopus)

Kopsavilkums

The thermodynamic and kinetic regularities of the intercalation of lithium into C-SiO ₂ nanocomposites are studied. The dependence of the differential capacity and kinetic intercalation parameters on the size of nanocomposite particles is established. According to theoretical analysis, the obtained results are explained as resulting from the quantum-mechanical effect of the interference blockage of the tunneling of an electron into a nonmetallic nanoparticle. An impedance model of processes and its parametric identification are given. A new class of electrochemical energy generators is proposed.

Oriģinālvaloda	Angļu
Lapas (no-līdz)	100-105
Lapu skaits	6
Žurnāls	Russian Journal of Physical Chemistry A
Sējums	86
Izdevuma numurs	1
DOIs	https://doi.org/10.1134/S0036024412010116
Publikācijas statuss	Publicēts - janv. 2012
Ārēji publicēts	Jā

Piekļuve Dokumentiem

10.1134/S0036024412010116

Citi faili un saites

Saite uz publikāciju Scopus

Citēt šo

@article{589e4ab8cca44d1696277aae3e5a2b07,

title = "Interference blockage of electron tunneling and pseudo-Faraday hypercapacity for C-SiO 2 nanocomposites",

abstract = "The thermodynamic and kinetic regularities of the intercalation of lithium into C-SiO 2 nanocomposites are studied. The dependence of the differential capacity and kinetic intercalation parameters on the size of nanocomposite particles is established. According to theoretical analysis, the obtained results are explained as resulting from the quantum-mechanical effect of the interference blockage of the tunneling of an electron into a nonmetallic nanoparticle. An impedance model of processes and its parametric identification are given. A new class of electrochemical energy generators is proposed.",

keywords = "intercalation, interference blockage, nanocomposite, tunneling",

author = "Grygorchak, \{I. I.\} and Lukiyanets, \{B. A.\} and Pidluzhna, \{A. Yu\} and Matulka, \{D. V.\} and Myronyuk, \{I. F.\}",

year = "2012",

month = jan,

doi = "10.1134/S0036024412010116",

language = "English",

volume = "86",

pages = "100--105",

journal = "Russian Journal of Physical Chemistry A",

issn = "0036-0244",

publisher = "Pleiades Publishing",

number = "1",

}

Interference blockage of electron tunneling and pseudo-Faraday hypercapacity for C-SiO ₂ nanocomposites. / Grygorchak, I. I.; Lukiyanets, B. A.; Pidluzhna, A. Yu u.c.
(gadā): Russian Journal of Physical Chemistry A, Sēj. 86, Nr. 1, 01.2012, lpp. 100-105.

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

TY - JOUR

T1 - Interference blockage of electron tunneling and pseudo-Faraday hypercapacity for C-SiO 2 nanocomposites

AU - Grygorchak, I. I.

AU - Lukiyanets, B. A.

AU - Pidluzhna, A. Yu

AU - Matulka, D. V.

AU - Myronyuk, I. F.

PY - 2012/1

Y1 - 2012/1

N2 - The thermodynamic and kinetic regularities of the intercalation of lithium into C-SiO 2 nanocomposites are studied. The dependence of the differential capacity and kinetic intercalation parameters on the size of nanocomposite particles is established. According to theoretical analysis, the obtained results are explained as resulting from the quantum-mechanical effect of the interference blockage of the tunneling of an electron into a nonmetallic nanoparticle. An impedance model of processes and its parametric identification are given. A new class of electrochemical energy generators is proposed.

AB - The thermodynamic and kinetic regularities of the intercalation of lithium into C-SiO 2 nanocomposites are studied. The dependence of the differential capacity and kinetic intercalation parameters on the size of nanocomposite particles is established. According to theoretical analysis, the obtained results are explained as resulting from the quantum-mechanical effect of the interference blockage of the tunneling of an electron into a nonmetallic nanoparticle. An impedance model of processes and its parametric identification are given. A new class of electrochemical energy generators is proposed.

KW - intercalation

KW - interference blockage

KW - nanocomposite

KW - tunneling

UR - https://www.scopus.com/pages/publications/84856303563

U2 - 10.1134/S0036024412010116

DO - 10.1134/S0036024412010116

M3 - Article

AN - SCOPUS:84856303563

SN - 0036-0244

VL - 86

SP - 100

EP - 105

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

IS - 1

ER -