Iodonium salts are key intermediates in Pd-catalyzed acetoxylation of pyrroles

Dmitrijs Lubriks; Igors Sokolovs; Edgars Suna

doi:10.1021/ol201665c

Iodonium salts are key intermediates in Pd-catalyzed acetoxylation of pyrroles

Dmitrijs Lubriks
, Igors Sokolovs
, Edgars Suna^*

^*Šī darba korespondējošais autors

Latvian Institute of Organic Synthesis

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

49 Atsauces (Scopus)

Kopsavilkums

A mild, room-temperature Pd-catalyzed acetoxylation of pyrroles with phenyliodonium acetate is described. The acetoxylation was found to proceed via the initial formation of pyrrolyl(phenyl)iodonium acetates, which were converted to acetoxypyrroles in the presence of Pd(OAc)₂. The acetoxylation could also be carried out as a one-pot sequential procedure without the isolation of the intermediate iodonium salts.

Oriģinālvaloda	Angļu
Lapas (no-līdz)	4324-4327
Lapu skaits	4
Žurnāls	Organic Letters
Sējums	13
Izdevuma numurs	16
DOIs	https://doi.org/10.1021/ol201665c
Publikācijas statuss	Publicēts - 19 aug. 2011
Ārēji publicēts	Jā

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title = "Iodonium salts are key intermediates in Pd-catalyzed acetoxylation of pyrroles",

abstract = "A mild, room-temperature Pd-catalyzed acetoxylation of pyrroles with phenyliodonium acetate is described. The acetoxylation was found to proceed via the initial formation of pyrrolyl(phenyl)iodonium acetates, which were converted to acetoxypyrroles in the presence of Pd(OAc)2. The acetoxylation could also be carried out as a one-pot sequential procedure without the isolation of the intermediate iodonium salts.",

author = "Dmitrijs Lubriks and Igors Sokolovs and Edgars Suna",

year = "2011",

month = aug,

day = "19",

doi = "10.1021/ol201665c",

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volume = "13",

pages = "4324--4327",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Iodonium salts are key intermediates in Pd-catalyzed acetoxylation of pyrroles

AU - Lubriks, Dmitrijs

AU - Sokolovs, Igors

AU - Suna, Edgars

PY - 2011/8/19

Y1 - 2011/8/19

N2 - A mild, room-temperature Pd-catalyzed acetoxylation of pyrroles with phenyliodonium acetate is described. The acetoxylation was found to proceed via the initial formation of pyrrolyl(phenyl)iodonium acetates, which were converted to acetoxypyrroles in the presence of Pd(OAc)2. The acetoxylation could also be carried out as a one-pot sequential procedure without the isolation of the intermediate iodonium salts.

AB - A mild, room-temperature Pd-catalyzed acetoxylation of pyrroles with phenyliodonium acetate is described. The acetoxylation was found to proceed via the initial formation of pyrrolyl(phenyl)iodonium acetates, which were converted to acetoxypyrroles in the presence of Pd(OAc)2. The acetoxylation could also be carried out as a one-pot sequential procedure without the isolation of the intermediate iodonium salts.

UR - https://www.scopus.com/pages/publications/80051705553

UR - http://pubs.acs.org/doi/abs/10.1021%252Fol201665c

U2 - 10.1021/ol201665c

DO - 10.1021/ol201665c

M3 - Article

AN - SCOPUS:80051705553

SN - 1523-7060

VL - 13

SP - 4324

EP - 4327

JO - Organic Letters

JF - Organic Letters

IS - 16

ER -

Iodonium salts are key intermediates in Pd-catalyzed acetoxylation of pyrroles

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