Lanthanide compounds with fluorinated aryloxide ligands: Near-infrared emission from Nd, Tm, and Er

Kieran Norton; G. A. Kumar; Jennifer L. Dilks; Thomas J. Emge; Richard E. Riman; Mikhail G. Brik; John G. Brennan

doi:10.1021/ic8020639

Lanthanide compounds with fluorinated aryloxide ligands: Near-infrared emission from Nd, Tm, and Er

Kieran Norton
, G. A. Kumar
, Jennifer L. Dilks
, Thomas J. Emge
, Richard E. Riman
, Mikhail G. Brik
, John G. Brennan

Rutgers - The State University of New Jersey, New Brunswick
University of Tartu

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

46 Atsauces (Scopus)

Kopsavilkums

Ln(OC ₆F ₅) ₃ form stable, isolable compounds with 1,2-dimethoxyethane (DME). Monomeric (DME) ₂Ln(OC ₆F ₅) ₃ (Ln = Nd, Er, Tm) adopt seven coordinate structures with two chelating DME and three terminal phenoxide ligands. Both (py) ₄Er(OC ₆F ₅) ₃ and (THF) ₃Yb(OC ₆F ₅) ₃ were also prepared and structurally characterized, with the latter being a mer-octahedral compound with bond lengths that are geometry dependent. Emission experiments on crystalline powders of the Nd(III), Tm(III), and Er(III) DME derivatives show that these compounds are highly emissive nearinfrared sources.

Oriģinālvaloda	Angļu
Lapas (no-līdz)	3573-3580
Lapu skaits	8
Žurnāls	Inorganic Chemistry
Sējums	48
Izdevuma numurs	8
DOIs	https://doi.org/10.1021/ic8020639
Publikācijas statuss	Publicēts - 20 apr. 2009
Ārēji publicēts	Jā

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@article{09cdb74427cc4010b15275c9d46f8380,

title = "Lanthanide compounds with fluorinated aryloxide ligands: Near-infrared emission from Nd, Tm, and Er",

abstract = "Ln(OC 6F 5) 3 form stable, isolable compounds with 1,2-dimethoxyethane (DME). Monomeric (DME) 2Ln(OC 6F 5) 3 (Ln = Nd, Er, Tm) adopt seven coordinate structures with two chelating DME and three terminal phenoxide ligands. Both (py) 4Er(OC 6F 5) 3 and (THF) 3Yb(OC 6F 5) 3 were also prepared and structurally characterized, with the latter being a mer-octahedral compound with bond lengths that are geometry dependent. Emission experiments on crystalline powders of the Nd(III), Tm(III), and Er(III) DME derivatives show that these compounds are highly emissive nearinfrared sources.",

author = "Kieran Norton and Kumar, \{G. A.\} and Dilks, \{Jennifer L.\} and Emge, \{Thomas J.\} and Riman, \{Richard E.\} and Brik, \{Mikhail G.\} and Brennan, \{John G.\}",

year = "2009",

month = apr,

day = "20",

doi = "10.1021/ic8020639",

language = "English",

volume = "48",

pages = "3573--3580",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "8",

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TY - JOUR

T1 - Lanthanide compounds with fluorinated aryloxide ligands

T2 - Near-infrared emission from Nd, Tm, and Er

AU - Norton, Kieran

AU - Kumar, G. A.

AU - Dilks, Jennifer L.

AU - Emge, Thomas J.

AU - Riman, Richard E.

AU - Brik, Mikhail G.

AU - Brennan, John G.

PY - 2009/4/20

Y1 - 2009/4/20

N2 - Ln(OC 6F 5) 3 form stable, isolable compounds with 1,2-dimethoxyethane (DME). Monomeric (DME) 2Ln(OC 6F 5) 3 (Ln = Nd, Er, Tm) adopt seven coordinate structures with two chelating DME and three terminal phenoxide ligands. Both (py) 4Er(OC 6F 5) 3 and (THF) 3Yb(OC 6F 5) 3 were also prepared and structurally characterized, with the latter being a mer-octahedral compound with bond lengths that are geometry dependent. Emission experiments on crystalline powders of the Nd(III), Tm(III), and Er(III) DME derivatives show that these compounds are highly emissive nearinfrared sources.

AB - Ln(OC 6F 5) 3 form stable, isolable compounds with 1,2-dimethoxyethane (DME). Monomeric (DME) 2Ln(OC 6F 5) 3 (Ln = Nd, Er, Tm) adopt seven coordinate structures with two chelating DME and three terminal phenoxide ligands. Both (py) 4Er(OC 6F 5) 3 and (THF) 3Yb(OC 6F 5) 3 were also prepared and structurally characterized, with the latter being a mer-octahedral compound with bond lengths that are geometry dependent. Emission experiments on crystalline powders of the Nd(III), Tm(III), and Er(III) DME derivatives show that these compounds are highly emissive nearinfrared sources.

UR - https://www.scopus.com/pages/publications/65349158320

U2 - 10.1021/ic8020639

DO - 10.1021/ic8020639

M3 - Article

AN - SCOPUS:65349158320

SN - 0020-1669

VL - 48

SP - 3573

EP - 3580

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 8

ER -

Lanthanide compounds with fluorinated aryloxide ligands: Near-infrared emission from Nd, Tm, and Er

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