New approach to the EPR of d1 ions in glasses

A. Bals; J. Kliava; J. Purans

doi:10.1088/0022-3719/13/17/001

New approach to the EPR of d¹ ions in glasses

A. Bals^*
, J. Kliava
, J. Purans

^*Šī darba korespondējošais autors

Plāno kārtiņu laboratorija, Cietvielu fizikas institūts

University of Latvia

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

13 Atsauces (Scopus)

Kopsavilkums

The EPR spectra of d¹ ions in glasses are computer simulated taking into account distributions of the components of the g tensor resulting from the structural disorder. By fitting to the experimental spectrum for Mo⁵⁺ ions in BaO-P₂O₅ glass, the following mean values of the spin Hamiltonian parameters are obtained: g_x0=1.941, g_y0=1.923, g_z0=1.888. The corresponding distribution widths are: Delta g_x=0.0077; Delta g_y=0.0067; Delta sig_z=0.0084. From these values, the authors estimate that the random variations of Mo-O distances in glass are about 1%.

Oriģinālvaloda	Angļu
Raksta numurs	001
Lapas (no-līdz)	L437-L441
Žurnāls	Journal of Physics C: Solid State Physics
Sējums	13
Izdevuma numurs	17
DOIs	https://doi.org/10.1088/0022-3719/13/17/001
Publikācijas statuss	Publicēts - 1980

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10.1088/0022-3719/13/17/001

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title = "New approach to the EPR of d1 ions in glasses",

abstract = "The EPR spectra of d1 ions in glasses are computer simulated taking into account distributions of the components of the g tensor resulting from the structural disorder. By fitting to the experimental spectrum for Mo5+ ions in BaO-P2O5 glass, the following mean values of the spin Hamiltonian parameters are obtained: gx0=1.941, gy0=1.923, gz0=1.888. The corresponding distribution widths are: Delta gx=0.0077; Delta gy=0.0067; Delta sigz=0.0084. From these values, the authors estimate that the random variations of Mo-O distances in glass are about 1\%.",

author = "A. Bals and J. Kliava and J. Purans",

year = "1980",

doi = "10.1088/0022-3719/13/17/001",

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TY - JOUR

T1 - New approach to the EPR of d1 ions in glasses

AU - Bals, A.

AU - Kliava, J.

AU - Purans, J.

PY - 1980

Y1 - 1980

N2 - The EPR spectra of d1 ions in glasses are computer simulated taking into account distributions of the components of the g tensor resulting from the structural disorder. By fitting to the experimental spectrum for Mo5+ ions in BaO-P2O5 glass, the following mean values of the spin Hamiltonian parameters are obtained: gx0=1.941, gy0=1.923, gz0=1.888. The corresponding distribution widths are: Delta gx=0.0077; Delta gy=0.0067; Delta sigz=0.0084. From these values, the authors estimate that the random variations of Mo-O distances in glass are about 1%.

AB - The EPR spectra of d1 ions in glasses are computer simulated taking into account distributions of the components of the g tensor resulting from the structural disorder. By fitting to the experimental spectrum for Mo5+ ions in BaO-P2O5 glass, the following mean values of the spin Hamiltonian parameters are obtained: gx0=1.941, gy0=1.923, gz0=1.888. The corresponding distribution widths are: Delta gx=0.0077; Delta gy=0.0067; Delta sigz=0.0084. From these values, the authors estimate that the random variations of Mo-O distances in glass are about 1%.

UR - https://www.scopus.com/pages/publications/4244141836

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DO - 10.1088/0022-3719/13/17/001

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