Peculiarities of the crystal structure evolution of Bifeo3-batio3 ceramics across structural phase transitions

Dmitry V. Karpinsky; Maxim V. Silibin; Sergei V. Trukhanov; Alex V. Trukhanov; Alexander L. Zhaludkevich; Siarhei I. Latushka; Dmitry V. Zhaludkevich; Vladimir A. Khomchenko; Denis O. Alikin; Alexander S. Abramov; Tomasz Maniecki; Waldemar Maniukiewicz; Martin Wolff; Volker Heitmann; Andrei L. Kholkin

doi:10.3390/nano10040801

Peculiarities of the crystal structure evolution of Bifeo₃-batio₃ ceramics across structural phase transitions

Dmitry V. Karpinsky^*
, Maxim V. Silibin
, Sergei V. Trukhanov
, Alex V. Trukhanov
, Alexander L. Zhaludkevich
, Siarhei I. Latushka
, Dmitry V. Zhaludkevich
, Vladimir A. Khomchenko
, Denis O. Alikin
, Alexander S. Abramov
, Tomasz Maniecki
, Waldemar Maniukiewicz
, Martin Wolff
, Volker Heitmann
, Andrei L. Kholkin

^*Šī darba korespondējošais autors

National Research University of Electronic Technology
Belarus Academy of Sciences
South Ural State University
Sechenov First Moscow State Medical University
University of Coimbra
Ural Federal University
Lodz University of Technology
Helmholtz-Zentrum Hereon
University of Aveiro

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

76 Atsauces (Scopus)

Kopsavilkums

Evolution of the crystal structure of ceramics BiFeO₃-BaTiO3 across the morphotropic phase boundary was analyzed using the results of macroscopic measuring techniques such as X-ray diffraction, differential scanning calorimetry, and differential thermal analysis, as well as the data obtained by local scale methods of scanning probe microscopy. The obtained results allowed to specify the concentration and temperature regions of the single phase and phase coexistent regions as well as to clarify a modification of the structural parameters across the rhombohedral-cubic phase boundary. The structural data show unexpected strengthening of structural distortion specific for the rhombohedral phase, which occurs upon dopant concentration and temperature-driven phase transitions to the cubic phase. The obtained results point to the non-monotonous character of the phase evolution, which is specific for metastable phases. The compounds with metastable structural state are characterized by enhanced sensitivity to external stimuli, which significantly expands the perspectives of their particular use.

Oriģinālvaloda	Angļu
Raksta numurs	801
Žurnāls	Nanomaterials
Sējums	10
Izdevuma numurs	4
DOIs	https://doi.org/10.3390/nano10040801
Publikācijas statuss	Publicēts - apr. 2020
Ārēji publicēts	Jā

Piekļuve Dokumentiem

10.3390/nano10040801

Citi faili un saites

Saite uz publikāciju Scopus

Citēt šo

Karpinsky, D. V., Silibin, M. V., Trukhanov, S. V., Trukhanov, A. V., Zhaludkevich, A. L., Latushka, S. I., Zhaludkevich, D. V., Khomchenko, V. A., Alikin, D. O., Abramov, A. S., Maniecki, T., Maniukiewicz, W., Wolff, M., Heitmann, V., & Kholkin, A. L. (2020). Peculiarities of the crystal structure evolution of Bifeo₃-batio₃ ceramics across structural phase transitions. Nanomaterials, 10(4), Zinātniskais raksts 801. https://doi.org/10.3390/nano10040801

@article{4b20993c87f24f9783177d38dda2f8bf,

title = "Peculiarities of the crystal structure evolution of Bifeo3-batio3 ceramics across structural phase transitions",

abstract = "Evolution of the crystal structure of ceramics BiFeO3-BaTiO3 across the morphotropic phase boundary was analyzed using the results of macroscopic measuring techniques such as X-ray diffraction, differential scanning calorimetry, and differential thermal analysis, as well as the data obtained by local scale methods of scanning probe microscopy. The obtained results allowed to specify the concentration and temperature regions of the single phase and phase coexistent regions as well as to clarify a modification of the structural parameters across the rhombohedral-cubic phase boundary. The structural data show unexpected strengthening of structural distortion specific for the rhombohedral phase, which occurs upon dopant concentration and temperature-driven phase transitions to the cubic phase. The obtained results point to the non-monotonous character of the phase evolution, which is specific for metastable phases. The compounds with metastable structural state are characterized by enhanced sensitivity to external stimuli, which significantly expands the perspectives of their particular use.",

keywords = "Crystal structure, Diffraction, Multiferroics, Phase transitions",

author = "Karpinsky, \{Dmitry V.\} and Silibin, \{Maxim V.\} and Trukhanov, \{Sergei V.\} and Trukhanov, \{Alex V.\} and Zhaludkevich, \{Alexander L.\} and Latushka, \{Siarhei I.\} and Zhaludkevich, \{Dmitry V.\} and Khomchenko, \{Vladimir A.\} and Alikin, \{Denis O.\} and Abramov, \{Alexander S.\} and Tomasz Maniecki and Waldemar Maniukiewicz and Martin Wolff and Volker Heitmann and Kholkin, \{Andrei L.\}",

note = "Publisher Copyright: {\textcopyright} 2020 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2020",

month = apr,

doi = "10.3390/nano10040801",

language = "English",

volume = "10",

journal = "Nanomaterials",

issn = "2079-4991",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "4",

}

Karpinsky, DV, Silibin, MV, Trukhanov, SV, Trukhanov, AV, Zhaludkevich, AL, Latushka, SI, Zhaludkevich, DV, Khomchenko, VA, Alikin, DO, Abramov, AS, Maniecki, T, Maniukiewicz, W, Wolff, M, Heitmann, V & Kholkin, AL 2020, 'Peculiarities of the crystal structure evolution of Bifeo₃-batio₃ ceramics across structural phase transitions', Nanomaterials, sēj. 10, Nr. 4, 801. https://doi.org/10.3390/nano10040801

TY - JOUR

T1 - Peculiarities of the crystal structure evolution of Bifeo3-batio3 ceramics across structural phase transitions

AU - Karpinsky, Dmitry V.

AU - Silibin, Maxim V.

AU - Trukhanov, Sergei V.

AU - Trukhanov, Alex V.

AU - Zhaludkevich, Alexander L.

AU - Latushka, Siarhei I.

AU - Zhaludkevich, Dmitry V.

AU - Khomchenko, Vladimir A.

AU - Alikin, Denis O.

AU - Abramov, Alexander S.

AU - Maniecki, Tomasz

AU - Maniukiewicz, Waldemar

AU - Wolff, Martin

AU - Heitmann, Volker

AU - Kholkin, Andrei L.

PY - 2020/4

Y1 - 2020/4

N2 - Evolution of the crystal structure of ceramics BiFeO3-BaTiO3 across the morphotropic phase boundary was analyzed using the results of macroscopic measuring techniques such as X-ray diffraction, differential scanning calorimetry, and differential thermal analysis, as well as the data obtained by local scale methods of scanning probe microscopy. The obtained results allowed to specify the concentration and temperature regions of the single phase and phase coexistent regions as well as to clarify a modification of the structural parameters across the rhombohedral-cubic phase boundary. The structural data show unexpected strengthening of structural distortion specific for the rhombohedral phase, which occurs upon dopant concentration and temperature-driven phase transitions to the cubic phase. The obtained results point to the non-monotonous character of the phase evolution, which is specific for metastable phases. The compounds with metastable structural state are characterized by enhanced sensitivity to external stimuli, which significantly expands the perspectives of their particular use.

AB - Evolution of the crystal structure of ceramics BiFeO3-BaTiO3 across the morphotropic phase boundary was analyzed using the results of macroscopic measuring techniques such as X-ray diffraction, differential scanning calorimetry, and differential thermal analysis, as well as the data obtained by local scale methods of scanning probe microscopy. The obtained results allowed to specify the concentration and temperature regions of the single phase and phase coexistent regions as well as to clarify a modification of the structural parameters across the rhombohedral-cubic phase boundary. The structural data show unexpected strengthening of structural distortion specific for the rhombohedral phase, which occurs upon dopant concentration and temperature-driven phase transitions to the cubic phase. The obtained results point to the non-monotonous character of the phase evolution, which is specific for metastable phases. The compounds with metastable structural state are characterized by enhanced sensitivity to external stimuli, which significantly expands the perspectives of their particular use.

KW - Crystal structure

KW - Diffraction

KW - Multiferroics

KW - Phase transitions

UR - https://www.scopus.com/pages/publications/85083958292

U2 - 10.3390/nano10040801

DO - 10.3390/nano10040801

M3 - Article

AN - SCOPUS:85083958292

SN - 2079-4991

VL - 10

JO - Nanomaterials

JF - Nanomaterials

IS - 4

M1 - 801

ER -