Solvothermal synthesis of Mn-based MOF materials: Application in high energy density lithium ion battery

L. Prettencia; E. Soundarrajan; S. Aadheeshwaran; S. Gnanam; M. Roselin Ranjitha; Smagul Zh Karazhanov; R. A. Kalaivani; S. Raghu

doi:10.1016/j.matlet.2023.135052

Solvothermal synthesis of Mn-based MOF materials: Application in high energy density lithium ion battery

L. Prettencia
, E. Soundarrajan
, S. Aadheeshwaran
, S. Gnanam
, M. Roselin Ranjitha
, Smagul Zh Karazhanov
, R. A. Kalaivani^*
, S. Raghu

^*Šī darba korespondējošais autors

Vels Institute of Science, Technology & Advanced Studies
Alagappa University
University of Madras
Institute for Energy Technology

Zinātniskās darbības rezultāts: Devums žurnālam › Zinātniskais raksts (žurnālā) › koleģiāli recenzēts

3 Atsauces (Scopus)

Kopsavilkums

The present work elaborates on the solvothermal synthesis of Li [Li_0.1Ni_0.3Mn_0.7] O₂ cathode materials derived from metal organic frameworks (LNMO-MOFs) with the novel use of complexing agents, 2-methylimidazole (MI) and 1,10-phenanthroline (PTH). Remarkably, these complexing agents increased the tap density and thereby enhanced the energy density significantly. Additionally, they exhibited low resistance 12.75 Ω, compatible particle size distribution (517.46 nm) and a specific capacity of 289.03 mhA g⁻¹ which are optimal for commercial use. Li [Li_0.1Ni_0.3Mn_0.7] O₂ surface enabled by 1,10-phenanthroline ensures a unique long cycling stability with a retention of 98.2 % even after 500 cycles. As a result, LNMO-MOFs have been demonstrated to be effective candidates for applications using lithium-ion batteries (LIBs).

Oriģinālvaloda	Angļu
Raksta numurs	135052
Žurnāls	Materials Letters
Sējums	351
DOIs	https://doi.org/10.1016/j.matlet.2023.135052
Publikācijas statuss	Publicēts - 15 nov. 2023
Ārēji publicēts	Jā

ANO IAM

Šis izpildes rezultāts palīdz sasniegt šādus ANO ilgtspējīgas attīstības mērķus (IAM)

7. IAM — Tīra Enerģija par Pieejamu Cenu

Piekļuve Dokumentiem

10.1016/j.matlet.2023.135052

Citi faili un saites

Saite uz publikāciju Scopus

Citēt šo

@article{507907a1d7da4a318c43465acdcb2e4d,

title = "Solvothermal synthesis of Mn-based MOF materials: Application in high energy density lithium ion battery",

abstract = "The present work elaborates on the solvothermal synthesis of Li [Li0.1Ni0.3Mn0.7] O2 cathode materials derived from metal organic frameworks (LNMO-MOFs) with the novel use of complexing agents, 2-methylimidazole (MI) and 1,10-phenanthroline (PTH). Remarkably, these complexing agents increased the tap density and thereby enhanced the energy density significantly. Additionally, they exhibited low resistance 12.75 Ω, compatible particle size distribution (517.46 nm) and a specific capacity of 289.03 mhA g−1 which are optimal for commercial use. Li [Li0.1Ni0.3Mn0.7] O2 surface enabled by 1,10-phenanthroline ensures a unique long cycling stability with a retention of 98.2 \% even after 500 cycles. As a result, LNMO-MOFs have been demonstrated to be effective candidates for applications using lithium-ion batteries (LIBs).",

keywords = "Complexing agents, LNMO-MOF, Solvothermal, Tap density",

author = "L. Prettencia and E. Soundarrajan and S. Aadheeshwaran and S. Gnanam and \{Roselin Ranjitha\}, M. and Karazhanov, \{Smagul Zh\} and Kalaivani, \{R. A.\} and S. Raghu",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier B.V.",

year = "2023",

month = nov,

day = "15",

doi = "10.1016/j.matlet.2023.135052",

language = "English",

volume = "351",

journal = "Materials Letters",

issn = "0167-577X",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Solvothermal synthesis of Mn-based MOF materials

T2 - Application in high energy density lithium ion battery

AU - Prettencia, L.

AU - Soundarrajan, E.

AU - Aadheeshwaran, S.

AU - Gnanam, S.

AU - Roselin Ranjitha, M.

AU - Karazhanov, Smagul Zh

AU - Kalaivani, R. A.

AU - Raghu, S.

PY - 2023/11/15

Y1 - 2023/11/15

N2 - The present work elaborates on the solvothermal synthesis of Li [Li0.1Ni0.3Mn0.7] O2 cathode materials derived from metal organic frameworks (LNMO-MOFs) with the novel use of complexing agents, 2-methylimidazole (MI) and 1,10-phenanthroline (PTH). Remarkably, these complexing agents increased the tap density and thereby enhanced the energy density significantly. Additionally, they exhibited low resistance 12.75 Ω, compatible particle size distribution (517.46 nm) and a specific capacity of 289.03 mhA g−1 which are optimal for commercial use. Li [Li0.1Ni0.3Mn0.7] O2 surface enabled by 1,10-phenanthroline ensures a unique long cycling stability with a retention of 98.2 % even after 500 cycles. As a result, LNMO-MOFs have been demonstrated to be effective candidates for applications using lithium-ion batteries (LIBs).

AB - The present work elaborates on the solvothermal synthesis of Li [Li0.1Ni0.3Mn0.7] O2 cathode materials derived from metal organic frameworks (LNMO-MOFs) with the novel use of complexing agents, 2-methylimidazole (MI) and 1,10-phenanthroline (PTH). Remarkably, these complexing agents increased the tap density and thereby enhanced the energy density significantly. Additionally, they exhibited low resistance 12.75 Ω, compatible particle size distribution (517.46 nm) and a specific capacity of 289.03 mhA g−1 which are optimal for commercial use. Li [Li0.1Ni0.3Mn0.7] O2 surface enabled by 1,10-phenanthroline ensures a unique long cycling stability with a retention of 98.2 % even after 500 cycles. As a result, LNMO-MOFs have been demonstrated to be effective candidates for applications using lithium-ion batteries (LIBs).

KW - Complexing agents

KW - LNMO-MOF

KW - Solvothermal

KW - Tap density

UR - https://www.scopus.com/pages/publications/85167830331

U2 - 10.1016/j.matlet.2023.135052

DO - 10.1016/j.matlet.2023.135052

M3 - Article

AN - SCOPUS:85167830331

SN - 0167-577X

VL - 351

JO - Materials Letters

JF - Materials Letters

M1 - 135052

ER -

Solvothermal synthesis of Mn-based MOF materials: Application in high energy density lithium ion battery

Kopsavilkums

ANO IAM

Piekļuve Dokumentiem

Citi faili un saites

Nospiedums

Citēt šo